Pd(II) conjugated chitosan nanofibre mats for application in Heck cross-coupling reactions

被引：55

作者：

Bradshaw, Michael ^{[1
]}

Zou, Jianli ^{[1
]}

Byrne, Lindsay ^{[2
]}

Iyer, K. Swaminathan ^{[1
]}

Stewart, Scott G.

Raston, Colin L. ^{[1
]}

机构：

[1] Univ Western Australia M313, Sch Biomed Biomol & Chem Sci, Ctr Strateg Nanofabricat, Crawley, WA 6009, Australia

[2] Univ Western Australia M313, Ctr Microscopy Characterisat & Anal, Crawley, WA 6009, Australia

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 45期

基金：

澳大利亚研究理事会;

关键词：

SUPPORTED PALLADIUM; CATALYSTS; COMPLEXES;

D O I：

10.1039/c1cc14717j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pd(II)-chitosan composite nanofibres of 62 +/- 9 nm diameter are efficient catalysts for Heck cross-coupling reactions. Using a model reaction of iodo-benzene and n-butyl acrylate, we demonstrate that this material can be used as a recyclable catalytic support with a very low loading of palladium (0.17 mol% Pd).

引用

页码：12292 / 12294

页数：3

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