Preparation of Cr2O3, MnO2, Fe2O3, NiO, CuO, and ZnO Oxides Using Their Glycine Complexes as Precursors for In Situ Thermal Decomposition

被引：28

作者：

Al-Wasidi, Asma S. ^{[1
]}

Naglah, Ahmed M. ^{[2
,3
]}

Kalmouch, Atef ^{[3
]}

Adam, Abdel Majid A. ^{[4
]}

Refat, Moamen S. ^{[4
,5
]}

Moustafa, Gaber O. ^{[3
,6
]}

机构：

[1] Princess Nourah BintAbduirahman Univ, Coll Sci, Dept Chem, Riyadh 11671, Saudi Arabia

[2] King Saud Univ, Coll Pharm, Dept Pharmaceut Chem, Drug Explorat & Dev Chair DEDC, Riyadh 11451, Saudi Arabia

[3] Natl Res Ctr, Peptide Chem Dept, Chem Ind Res Div, Cairo 12622, Egypt

[4] Taif Univ, Fac Sci, Dept Chem, POB 888, At Taif 21974, Saudi Arabia

[5] Port Said Univ, Fac Sci, Dept Chem, Port Said, Egypt

[6] Nahda Univ, New Benisuef City 62521, Beni Sueif, Egypt

来源：

EGYPTIAN JOURNAL OF CHEMISTRY | 2020年 / 63卷 / 03期

关键词：

Chelation; FT-IR; Glycine; Metal oxide; Thermal decomposition; AMINO-ACID DERIVATIVES; OXIDATION; PEPTIDES; ANTIBODY;

D O I：

10.21608/ejchem.2020.20679.2240

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

GLYCINE (Gly) complexes play an important role in human life. Zn(II), Cu(II), Ni(II), Fe(III), Mn(II), and Cr(III) complexes were synthesized with glycine (Gly). These complexes were characterized by infrared spectroscopy (FT-IR). Based on the stoichiometric data, Gly form a chelate complex in a bidentate fashion at a 1:3 ratio with the trivalent metal ions [Cr(III), Fe(III)] and a 1:2 ratio with the divalent ones [Mn(II), Ni(II), Cu(II) and Zn(II)]. Metal oxides were derived from each of the Gly complexes using thermal decomposition at 800 degrees C. FT-IR analysis of the resulting solids revealed their formation in pure form.

引用

页码：1109 / 1118

页数：10

共 47 条

[1]

Abo-Ghalia M.H., 2020, Molecules, V25, P1253

[2]

Abo-Ghalia MH, 2017, LAT AM J PHARM, V36, P1957

[3]

Al-Jeboori F.H.A., 2013, Journal of Chemical and Pharmaceutical Research, V5, P318

[4]

Al-Jeboori F.H.A., 2013, J Chem Pharm Res, V5, P172

[5]

Al-Salem H. S. A., 2017, J COMPUT THEOR NANOS, V14, P3958, DOI [10.1166/jctn.2017.6702, DOI 10.1166/jctn.2017.6702]

[6]

Al-Wasidi A.S., 2020, EGYPT J CHEM, V63

[7] Synthesis and characterization of NiO nanoparticles by sol-gel method [J].

Alagiri, M. ;

Ponnusamy, S. ;

Muthamizhchelvan, C. .

JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2012, 23 (03) :728-732

[8] Glycine Metabolism and Its Alterations in Obesity and Metabolic Diseases [J].

Alves, Anais ;

Bassot, Arthur ;

Bulteau, Anne-Laure ;

Pirola, Luciano ;

Morio, Beatrice .

NUTRIENTS, 2019, 11 (06)

[9] Design, Synthesis and Docking Studies of Novel Macrocyclic Pentapeptides as Anticancer Multi-Targeted Kinase Inhibitors [J].

Amr, Abd El-Galil E. ;

Abo-Ghalia, Mohamed H. ;

Moustafa, Gaber O. ;

Al-Omar, Mohamed A. ;

Nossier, Eman S. ;

Elsayed, Elsayed A. .

MOLECULES, 2018, 23 (10)

[10]

[Anonymous], BIOCHEMISTRY

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