Towards highly efficient and low-cost oxygen evolution reaction electrocatalysts: An effective method of electronic waste management by utilizing waste Cu cable wires

被引:51
作者
Babar, Pravin [1 ]
Lokhande, Abhishek [1 ]
Karade, Vijay [1 ]
Pawar, Bharati [2 ]
Gang, Myeng Gil [1 ]
Pawar, Sambhaji [2 ]
Kim, Jin Hyeok [1 ]
机构
[1] Chonnam Natl Univ, Dept Mat Sci & Engn, Optoelect Convergence Res Ctr, Gwangju 500757, South Korea
[2] Dongguk Univ, Div Phys & Semicond Sci, Seoul 100715, South Korea
关键词
Waste Cu cable wire; Oxygen evolution reaction; Cu(OH)(2); NiFe hydroxide; Nanowires; REACTION OER ELECTROCATALYST; BIFUNCTIONAL ELECTROCATALYST; IRON OXYHYDROXIDE; ENERGY-CONVERSION; WATER OXIDATION; CATALYSTS; GENERATION; NANOSHEETS; HYDROXIDE; MECHANISM;
D O I
10.1016/j.jcis.2018.10.079
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Currently, electronic waste (e-waste) is the world's most challenging and rapidly growing problem in the waste stream. To develop an alternative way to use e-waste (waste copper (Cu) wires) to accelerate the oxygen evolution reaction (OER) of water electrolysis, the waste Cu wires are used as a low-cost current collector. We demonstrate a simple electrodeposition process to deposit nickel-iron hydroxide (NiFe LDH) nanosheets on self-supported copper hydroxide (Cu(OH)(2)/Cu) nanowires grown via chemical-oxidation on waste Cu wire. Benefiting from the efficient electron transport, high mass activity, and surface area this electrocatalyst exhibits an efficient OER performance with a low overpotential of 275 mV and 390 mV at 20 and 100 mA cm(-2) respectively, with excellent stability. This work provides a promising pathway to recycle e-waste into value-added resources in various energy conversion applications. (C) 2018 Published by Elsevier Inc.
引用
收藏
页码:43 / 49
页数:7
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