LiCB11Me12:: A catalyst for pericyclic rearrangements

被引：63

作者：

Moss, S

King, BT

de Meijere, A

Kozhushkov, SI

Eaton, PE

Michl, J ^{[1
]}

机构：

[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

[2] Univ Gottingen, Inst Organ Chem, D-37077 Gottingen, Germany

[3] Univ Chicago, Dept Chem, Chicago, IL 60637 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 15期

关键词：

D O I：

10.1021/ol0161864

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Benzene and 1,2-dichloroethane solutions of the Li+ salt of the weakly coordinating anion CB11Me12- catalyze the rearrangement of cubane to cuneane, quadricyclane to norbornadiene, basketene to Nenitzescu's hydrocarbon, and diademane to triquinacene. The Claisen rearrangement of phenyl allyl ether is also strongly accelerated.

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页码：2375 / 2377

页数：3

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