Sulfonic acid functionalised SBA-15 as catalysts for Beckmann rearrangement and esterification reaction

被引:24
|
作者
Zhao, Wei [1 ]
Salame, Petra [2 ]
Launay, Franck [2 ]
Gedeon, Antoine [2 ]
Hao, Zhengping [1 ]
机构
[1] Chinese Acad Sci, Ecoenvironm Sci Res Ctr, Beijing 100085, Peoples R China
[2] Univ Paris 06, UMR 7142, Lab SIEN, CNRS, F-75252 Paris, France
关键词
Beckmann rearrangement; esterification reaction; SBA-15; arenesulfonic acids;
D O I
10.1007/s10934-007-9115-5
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Hybrid inorganic-organic solid acid materials SBA-15-Ph-SO3H were synthesized by the directly co-condensation method under the acid medium. The resulting materials perform well both in the liquid phase Beckmann rearrangement (The yield is 32.3%) and esterification reaction (The yield is 95.5%). And more, the catalysts show the different catalytic performance in these two reactions.
引用
收藏
页码:139 / 143
页数:5
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