Effects of Monocarboxylic Acid Additives on Synthesizing Metal-Organic Framework NH2-MIL-125 with Controllable Size and Morphology

被引：67
作者：
Hu, Shen [1 ]
Liu, Min [1 ]
Guo, Xinwen [1 ]
Li, Keyan [1 ]
Han, Yitong [1 ]
Song, Chunshan [1 ,2 ,3 ]
Zhang, Guoliang [4 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, PSU DUT Joint Ctr Energy Res, State Key Lab Fine Chem, Dalian 116024, Peoples R China
[2] Penn State Univ, PSU DUT Joint Ctr Energy Res, EMS Energy Inst, University Pk, PA 16802 USA
[3] Penn State Univ, Dept Energy & Mineral Engn, University Pk, PA 16802 USA
[4] Zhejiang Univ Technol, Coll Biol & Environm Engn, Hangzhou 310014, Zhejiang, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2017年 / 17卷 / 12期
基金：
中国国家自然科学基金;
关键词：
ASSISTED LINKER EXCHANGE; COORDINATION MODULATION; FACILE SYNTHESIS; GAS-ADSORPTION; UIO-66; CRYSTALS; DYES; DEFECTS; MOF; CRYSTALLIZATION;
D O I：
10.1021/acs.cgd.7b01250
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The effect of monocarboxylic acids on synthesizing NH2-MIL-125 is systematically studied for the first time in this work, and the fantastic results are discussed in detail. We found that a small molecular acid (acetic acid, thioglycolic acid) mostly affects the morphology changes of NH2-MIL-125, while the pseudolinker acid (p-toluylic acid, benzoic acid) has a significantly impact on the crystal size on account of the nucleation and the crystal growth rates. Ar sorption measurement and transmission electron microscopy characterization show that samples synthesized with pseudolinker acid as additives have a hierarchical structure owing to the internal defects or caves formed in the crystal. These samples also show an excellent performance for the removal of organic pollutants by the combined effects of adsorption and photodegradation.
引用
收藏
页码：6586 / 6595
页数：10
相关论文
共 53 条
[1]   Toxic gas removal - metal-organic frameworks for the capture and degradation of toxic gases and vapours [J].
Barea, Elisa ;
Montoro, Carmen ;
Navarro, Jorge A. R. .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5419-5430
[2]   Water Stability and Adsorption in Metal-Organic Frameworks [J].
Burtch, Nicholas C. ;
Jasuja, Himanshu ;
Walton, Krista S. .
CHEMICAL REVIEWS, 2014, 114 (20) :10575-10612
[3]   Size- and morphology-controlled NH2-MIL-53(Al) prepared in DMF-water mixed solvents [J].
Cheng, Xinquan ;
Zhang, Anfeng ;
Hou, Keke ;
Liu, Min ;
Wang, Yingxia ;
Song, Chunshan ;
Zhang, Guoliang ;
Guo, Xinwen .
DALTON TRANSACTIONS, 2013, 42 (37) :13698-13705
[4]   Tuning the aspect ratio of NH2-MIL-53(Al) microneedles and nanorods via coordination modulation [J].
Chin, Jia Min ;
Chen, Eric Yu ;
Menon, Ajay Govinda ;
Tan, Han Yang ;
Hor, Andy Tzi Sum ;
Schreyer, Martin Karl ;
Xu, Jianwei .
CRYSTENGCOMM, 2013, 15 (04) :654-657
[5]   Heterogeneity within Order in Crystals of a Porous Metal-Organic Framework [J].
Choi, Kyung Min ;
Jeon, Hyung Joon ;
Kang, Jeung Ku ;
Yaghi, Omar M. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (31) :11920-11923
[6]   Engineering Metal Organic Frameworks for Heterogeneous Catalysis [J].
Corma, A. ;
Garcia, H. ;
Llabres i Xamena, F. X. L. I. .
CHEMICAL REVIEWS, 2010, 110 (08) :4606-4655
[7]   A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate [J].
Dan-Hardi, Meenakshi ;
Serre, Christian ;
Frot, Theo ;
Rozes, Laurence ;
Maurin, Guillaume ;
Sanchez, Clement ;
Ferey, Gerard .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (31) :10857-+
[8]  
Deria P, 2014, CHEM SOC REV, V43, P5896, DOI [10.1039/C4CS00067F, 10.1039/c4cs00067f]
[9]   Controlled Multiscale Synthesis of Porous Coordination Polymer in Nano/Micro Regimes [J].
Diring, Stephane ;
Furukawa, Shuhei ;
Takashima, Yohei ;
Tsuruoka, Takaaki ;
Kitagawa, Susumu .
CHEMISTRY OF MATERIALS, 2010, 22 (16) :4531-4538
[10]   Visible-light-induced aerobic photocatalytic oxidation of aromatic alcohols to aldehydes over Ni-doped NH2-MIL-125(Ti) [J].
Fu, Yanghe ;
Sun, Long ;
Yang, Huan ;
Xu, Lai ;
Zhang, Fumin ;
Zhu, Weidong .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 187 :212-217
123456