Near-IR absorbing donor-acceptor charge-transfer gallium complex, an example from non-transition metal chemistry

被引：18

作者：

Maleeva, Arina, V ^{[1
]}

Ershova, Irina, V ^{[1
]}

Trofimova, Olesya Yu ^{[1
]}

Arsenyeva, Kseniya, V ^{[1
]}

Yakushev, Ilya A. ^{[2
]}

Piskunov, Alexandr, V ^{[1
]}

机构：

[1] Russian Acad Sci, GA Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia

[2] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 01期

关键词：

gallium; redox-active ligand; catecholate; diimine; X-ray diffraction; electronic spectroscopy; ELECTRONIC-STRUCTURE; INFRARED ELECTROCHROMISM; CRYSTAL-STRUCTURES; DIIMINE COMPLEXES; EXCITED-STATES; LIGAND; PLATINUM(II); OXIDATION; PT(II); CATECHOLATE;

D O I：

10.1016/j.mencom.2022.01.027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gallium (III) catecholates with bipyridine ligand [(3,5-Cat)Ga(bipy)(2)]I and (3,6-Cat)GaI(bipy) (Cat is di-tert-butylcatecholate) were synthesized and characterized by single-crystal X-ray diffraction. The appearance of near-infrared ligand-to-ligand charge transfer for pentacoo rdi n ate complex was observed.

引用

页码：83 / 86

页数：4

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