共 41 条
Ecklonia cava based mesoporous activated carbon for high-rate energy storage devices
被引:11
作者:
Kim, Kue-Ho
[1
]
Shin, Dong-Yo
[2
]
Ahn, Hyo-Jin
[1
,2
]
机构:
[1] Seoul Natl Univ Sci & Technol, Dept Mat Sci & Engn, Seoul 01811, South Korea
[2] Seoul Natl Univ Sci & Technol, Convergence Inst Biomed Engn & Biomat, Program Mat Sci & Engn, Seoul 01811, South Korea
基金:
新加坡国家研究基金会;
关键词:
Electrical double-layer capacitors;
Activated carbon;
Ecklonia cava;
Mesoporous structure;
Rate performance;
HIGH-SURFACE-AREA;
POROUS CARBON;
PERFORMANCE;
SUPERCAPACITOR;
ELECTRODES;
NANOFIBERS;
TEMPLATE;
BIOMASS;
D O I:
10.1016/j.jiec.2020.01.027
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Activated carbon has received enormous global attention as an electrode material for electrical double layer capacitors (EDLCs) due to its superior electrochemical performance. But while manufacturing high-quality activated carbon as an electrode material, overcoming limitations such as depletion of raw material resources, poor high-rate performance, and cycle stability is still a significant challenge. To address these limitations, we firstly suggest a novel mesoporous activated carbon derived from ecklonia cava (Meso-ACDE) using an acid-base reaction and KOH activation processes. The optimized Meso-ACDE electrode showed a superior specific capacitance of 182 F g(-1), at the current density of 0.2 A g(-1) and a high-rate capacitance of 154 F g(-1) at the current density of 20.0 A g(-1) with an excellent cycling stability up to 2000 cycles. The enhanced electrochemical performance of the Meso-ACDE electrode was mainly attributed to the well-developed mesoporous structure with a high concentration of oxygen related functional groups, which were acquired during the activation process. Thus, we believe that the Meso-ACDE could be a promising alternative to conventional activated carbon for high-performance EDLCs. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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页码:393 / 399
页数:7
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