Ecklonia cava based mesoporous activated carbon for high-rate energy storage devices

被引:11
作者
Kim, Kue-Ho [1 ]
Shin, Dong-Yo [2 ]
Ahn, Hyo-Jin [1 ,2 ]
机构
[1] Seoul Natl Univ Sci & Technol, Dept Mat Sci & Engn, Seoul 01811, South Korea
[2] Seoul Natl Univ Sci & Technol, Convergence Inst Biomed Engn & Biomat, Program Mat Sci & Engn, Seoul 01811, South Korea
基金
新加坡国家研究基金会;
关键词
Electrical double-layer capacitors; Activated carbon; Ecklonia cava; Mesoporous structure; Rate performance; HIGH-SURFACE-AREA; POROUS CARBON; PERFORMANCE; SUPERCAPACITOR; ELECTRODES; NANOFIBERS; TEMPLATE; BIOMASS;
D O I
10.1016/j.jiec.2020.01.027
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Activated carbon has received enormous global attention as an electrode material for electrical double layer capacitors (EDLCs) due to its superior electrochemical performance. But while manufacturing high-quality activated carbon as an electrode material, overcoming limitations such as depletion of raw material resources, poor high-rate performance, and cycle stability is still a significant challenge. To address these limitations, we firstly suggest a novel mesoporous activated carbon derived from ecklonia cava (Meso-ACDE) using an acid-base reaction and KOH activation processes. The optimized Meso-ACDE electrode showed a superior specific capacitance of 182 F g(-1), at the current density of 0.2 A g(-1) and a high-rate capacitance of 154 F g(-1) at the current density of 20.0 A g(-1) with an excellent cycling stability up to 2000 cycles. The enhanced electrochemical performance of the Meso-ACDE electrode was mainly attributed to the well-developed mesoporous structure with a high concentration of oxygen related functional groups, which were acquired during the activation process. Thus, we believe that the Meso-ACDE could be a promising alternative to conventional activated carbon for high-performance EDLCs. (C) 2020 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:393 / 399
页数:7
相关论文
共 41 条
  • [1] Hierarchically mesoporous activated carbon prepared from the dissolution of zinc oxide for high-rate electrical double layer capacitors
    An, Geon-Hyoung
    Lee, Do-Young
    Ahn, Hyo-Jin
    [J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2018, 65 : 423 - 428
  • [2] Vanadium nitride encapsulated carbon fibre networks with furrowed porous surfaces for ultrafast asymmetric supercapacitors with robust cycle life
    An, Geon-Hyoung
    Lee, Do-Young
    Ahn, Hyo-Jin
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (37) : 19714 - 19720
  • [3] Well-dispersed iron nanoparticles exposed within nitrogen-doped mesoporous carbon nanofibers by hydrogen-activation for oxygen-reduction reaction
    An, Geon-Hyoung
    Lee, Eun-Hwan
    Ahn, Hyo-Jin
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 682 : 746 - 752
  • [4] Activated mesoporous carbon nanofibers fabricated using water etching-assisted templating for high-performance electrochemical capacitors
    An, Geon-Hyoung
    Koo, Bon-Ryul
    Ahn, Hyo-Jin
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (09) : 6587 - 6594
  • [5] Hierarchical architecture of hybrid carbon-encapsulated hollow manganese oxide nanotubes with a porous-wall structure for high-performance electrochemical energy storage
    An, Geon-Hyoung
    Sohn, Jung Inn
    Ahn, Hyo-Jin
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (06) : 2049 - 2054
  • [6] Surface modification of RuO2 nanoparticles-carbon nanofiber composites for electrochemical capacitors
    An, Geon-Hyoung
    Ahn, Hyo-Jin
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2015, 744 : 32 - 36
  • [7] Electrochemical properties for high surface area and improved electrical conductivity of platinum-embedded porous carbon nanofibers
    An, Geon-Hyoung
    Ahn, Hyo-Jin
    Hong, Woong-Ki
    [J]. JOURNAL OF POWER SOURCES, 2015, 274 : 536 - 541
  • [8] Carbon nanofiber/cobalt oxide nanopyramid core-Shell nanowires for high-performance lithium-ion batteries
    An, Geon-Hyoung
    Ahn, Hyo-Jin
    [J]. JOURNAL OF POWER SOURCES, 2014, 272 : 828 - 836
  • [9] The preparation of PANI/CA composite electrode material for supercapacitors and its electrochemical performance
    An, Hongfang
    Wang, Ying
    Wang, Xianyou
    Li, Na
    Zheng, Liping
    [J]. JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2010, 14 (04) : 651 - 657
  • [10] Synthesis and characterizations of activated carbon from Wisteria sinensis seeds biomass for energy storage applications
    Awasthi, Ganesh Prasad
    Bhattarai, Deval Prasad
    Maharjan, Bikendra
    Kim, Kyung-Suk
    Park, Chan Hee
    Kim, Cheol Sang
    [J]. JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2019, 72 : 265 - 272