Chemical insights from EPR spectra of organometallic radicals and radical ions

被引：10

作者：

Rieger, AL ^{[1
]}

Rieger, PH ^{[1
]}

机构：

[1] Brown Univ, Dept Chem, Providence, RI 02912 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 02期

关键词：

D O I：

10.1021/om030565e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A review of applications of electron paramagnetic resonance (EPR) to organometallics is given, covering about 35 years of the authors' work. The review includes applications where the conclusions are mainly a picture of electronic structure, though often knowledge of the singly occupied molecular orbital (SOMO) has implications for molecular structure. Included in the review are discussions of addition of a second phosphite ligand to [Co{S2C2(CF3)(2)}P(OMe)(3)] and a unique example of electronic isomerism (summarized on the cover).

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页码：154 / 162

页数：9

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