Structural characterization, thermal and mechanical properties of polyurethane/CoAl layered double hydroxide nanocomposites prepared via in situ polymerization

被引：65

作者：

Guo, Shuzhong ^{[1
]}

Zhang, Chao ^{[1
]}

Peng, Hongdan ^{[1
]}

Wang, Weizhi ^{[1
]}

Liu, Tianxi ^{[1
]}

机构：

[1] Fudan Univ, Dept Macromol Sci, Minist Educ, Key Lab Mol Engn Polymers, Shanghai 200433, Peoples R China

来源：

COMPOSITES SCIENCE AND TECHNOLOGY | 2011年 / 71卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Nanocomposites; Thermal properties; Mechanical properties; SOLUTION INTERCALATION; RUBBER; POLYPROPYLENE; EXFOLIATION; MORPHOLOGY;

D O I：

10.1016/j.compscitech.2010.12.001

中图分类号：

TB33 [复合材料];

学科分类号：

摘要：

Dodecyl sulfate (DS), one kind of sulfate anion, was intercalated in the interlayer space between CoAl layered double hydroxide (CoAl-LDH) layers, and then polyurethane (PU) based nanocomposites were prepared by in situ intercalation polymerization with different amounts of the organo-modified CoAl-LDH. An exfoliated dispersion of CoAl-LDH layers in PU matrix was verified by the disappearance of the (0 0 3) reflection of the XRD results when the LDH loading was less than 2.0 wt%. Tensile testing indicated that excellent mechanical properties of PU/LDH nanocomposites were achieved. The weak alkaline catalysis of DS to polyurethane chains, combined with the dehydration and structural degradation of the LDH below 300 degrees C, accounted for the process of proceeded degradation as shown in TGA results. The real-time FTIR revealed that the as-prepared nanocomposites had a slower thermo-oxidative rate than neat PU from 160 degrees C to 340 degrees C, probably due to the barrier effect of LDH layers. These results suggested potential applications of CoAl-LDH as a promising flame retardant in PUs. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：791 / 796

页数：6

共 28 条

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