Structural, Electronic, and Magnetic Properties of Novel Spin-Crossover Complex: Fe(butyl nicotinate)2[Au(CN)2]2

被引：12

作者：

Ueno, Shoutaro ^{[1
]}

Kawasaki, Takeshi ^{[1
]}

Okabayashi, Jun ^{[2
]}

Kitazawa, Takafumi ^{[1
,3
]}

机构：

[1] Toho Univ, Dept Chem, Funabashi, Chiba 2748510, Japan

[2] Univ Tokyo, Res Ctr Spectrochem, Bunkyo Ku, Tokyo 1130033, Japan

[3] Toho Univ, Res Ctr Mat Integrated Properties, Funabashi, Chiba 2748510, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2015年 / 88卷 / 04期

关键词：

COORDINATION POLYMER; HOFMANN-TYPE; TRANSITION; 2-STEP; BEHAVIOR;

D O I：

10.1246/bcsj.20140360

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We have synthesized a novel bilayered Hofmann-type 2D network complex Fe(butyl nicotinate)(2)[Au(CN)(2)](2) (I). The single crystals of I reveal a spin-crossover (SCO) transition around 200 K. Temperature-dependent X-ray absorption fine structure (XAFS) spectra indicate that I displays both SCO and aurophilic interaction properties.

引用

页码：551 / 553

页数：3

共 29 条

[1] Spin-crossover behavior in cyanide-bridged Iron(II)-Gold(I) bimetallic 2D hofmann-like metal-organic frameworks [J].

Agusti, Gloria ;

Munoz, M. Carmen ;

Gaspar, Ana B. ;

Real, Jose A. .

INORGANIC CHEMISTRY, 2008, 47 (07) :2552-2561

[2] Oxidative Addition of Halogens on Open Metal Sites in a Microporous Spin-Crossover Coordination Polymer [J].

Agusti, Gloria ;

Ohtani, Ryo ;

Yoneda, Ko ;

Gaspar, Ana B. ;

Ohba, Masaaki ;

Sanchez-Royo, Juan F. ;

Carmen Munoz, M. ;

Kitagawa, Susumu ;

Real, Jose A. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (47) :8944-8947

[3] Two-Step Thermal Spin Transition and LIESST Relaxation of the Polymeric Spin-Crossover Compounds Fe(X-py)2[Ag(CN)2]2 (X=H, 3-methyl, 4-methyl, 3,4-dimethyl, 3-Cl) [J].

Alberto Rodriguez-Velamazan, J. ;

Carbonera, Chiara ;

Castro, Miguel ;

Palacios, Elias ;

Kitazawa, Takafumi ;

Letard, Jean-Francois ;

Burriel, Ramon .

CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (29) :8785-8796

[4]

[Anonymous], 1997, CHEM LETT

[5] [Fe(TPT)2/3{MI(CN)2}2]•nSolv (MI=Ag, Au): New Bimetallic Porous Coordination Polymers with Spin-Crossover Properties [J].

Arcis-Castillo, Zulema ;

Carmen Munoz, M. ;

Molnar, Gabor ;

Bousseksou, Azzedine ;

Antonio Real, Jose .

CHEMISTRY-A EUROPEAN JOURNAL, 2013, 19 (21) :6851-6861

[6] Guidelines to design new spin crossover materials [J].

Atmani, Chahlae ;

El Hajj, Fatima ;

Benmansour, Samia ;

Marchivie, Mathieu ;

Triki, Smail ;

Conan, Francoise ;

Patinec, Veronique ;

Handel, Henri ;

Dupouy, Gaelle ;

Gomez-Garcia, Carlos J. .

COORDINATION CHEMISTRY REVIEWS, 2010, 254 (13-14) :1559-1569

[7]

COULTHARD I, 1997, J PHYS IV, V7, pC 2

[8]

Galet A., 2004, CHEM COMMUN, P2268

[9] Spin crossover phenomena in Fe(II) complexes [J].

Gütlich, P ;

Garcia, Y ;

Goodwin, HA .

CHEMICAL SOCIETY REVIEWS, 2000, 29 (06) :419-427

[10] THERMAL AND OPTICAL SWITCHING OF IRON(II) COMPLEXES [J].

GUTLICH, P ;

HAUSER, A ;

SPIERING, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (20) :2024-2054

← 1 2 3 →