Experiences with interlaboratory GPC experiments

被引:35
作者
Bruessau, RJ
机构
[1] BASF Aktiengesellschaft, Kunststofflaboratorium, D - 67056 Ludwigshafen am Rhein
关键词
D O I
10.1002/masy.19961100103
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Based on some round robin experiments organized in the last years by a DIN working group and by the IUPAC working party IV.2.2, the paper discusses measures for getting a better interlaboratory reproducibility of GPC results. The most important points are: selecting columns according to their separation selectivity and range avoiding artifacts in the distribution curves, caused by gaps in the pore volume distribution avoiding adsorption and memory effects calibration: using calibration standards of high quality selecting suitable calibration points checking the influence of the injected concentration selecting a common detector data treatment, especially finding the correct baseline preparing a detailed data report according to a uniform schedule.
引用
收藏
页码:15 / 32
页数:18
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