Formation of the iodine monoxide radical from gas-phase reactions of iodoalkyl radicals with molecular oxygen

被引：12

作者：

Enami, Shinichi ^{[1
]}

Yamanaka, Takashi

Hashimoto, Satoshi

Kawasaki, Masahiro

Tonokura, Kenichi

Tachikawa, Hiroto

机构：

[1] CALTECH, WM Keck Lab, Pasadena, CA 91125 USA

[2] Kyoto Univ, Dept Mol Engn, Kyoto 6158510, Japan

[3] Univ Tokyo, Ctr Environm Sci, Tokyo 1130033, Japan

[4] Hokkaido Univ, Fac Engn, Dept Chem Mat, Sapporo, Hokkaido 0608628, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2007年 / 445卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2007.08.025

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Formation of the iodine monoxide radical (IO) was observed during the reaction of iodoalkyl radicals (RCHI) or cyclo-C6H10I radical with O-2 at 298 K using cavity ring-down spectroscopy, where R stands for CnH2n+l (n = 0-3). The yields of IO from the reactions of various RCH2I species with Cl atom in the presence of O-2 were determined. The energy level diagrams derived from theoretical calculations for each individual reaction support the formation of IO radicals via a direct RCHI radical oxidation pathway. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：152 / 156

页数：5

共 23 条

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