Gas-phase reactions of tetrachlorogermane with chlorothiophenes in the presence of hexachlorodisilane. Synthesis of thienylchlorogermanes

被引：1

作者：

Chernyshev, E. A. ^{[1
]}

Komalenkova, N. G. ^{[1
]}

Yakovleva, G. N. ^{[1
]}

Bykovchenko, V. G. ^{[1
]}

Dubikhina, M. A. ^{[1
]}

Lakhtin, V. G. ^{[1
]}

机构：

[1] State Res Inst Chem & Technol Organoelement Cpds, Moscow 111123, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2007年 / 77卷 / 08期

关键词：

Thiophene; SiCl; Phene; GeCl; Germyl;

D O I：

10.1134/S1070363207080051

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Gas-phase reactions of dichlorogermylenes formed in the GeCl4-Si2Cl6 system with 2-chlorothiophene, 2,5-dichlorothiophene, 2,5-dichloro-3-methylthiophene, and 5-chloro-2-trimethylsilylthiophene is studied. It is shown that :GeCl2 is inserted into the chlorothiophene C-Cl bond to form the derivatives containing one or two trichlorogermyl groups. In the reaction with 5-chloro-2-trimethylsilylthiophene, the insertion of :GeCl2 into the C-Cl bond yielding 5-trichlorogermyl-2-trimethylsilylthiophene is accompanied by the exchange of the Me3Si group with the trichlorogermyl group to form 2,5-bis(trichlorogermyl)thiophene. The reactions occurring in the course of the synthesis of thienylchlorogermanes are considered.

引用

页码：1332 / 1336

页数：5

共 8 条

[1] Gas-phase reactions of tetrachlorogermane with chlorothiophenes in the presence of hexachlorodisilane. Synthesis of thienylchlorogermanes
E. A. Chernyshev
N. G. Komalenkova
G. N. Yakovleva
V. G. Bykovchenko
M. A. Dubikhina
V. G. Lakhtin
Russian Journal of General Chemistry, 2007, 77 : 1332 - 1336
[2] Reaction of tetrachlorogermane with thienyl- and phenylchlorosilanes in presence of aluminum chloride. Synthesis of thienylchlorogermanes
Lakhtin, V. G.
Vorob'eva, M. I.
Gordeev, E. G.
Ushakov, V. N.
Kirillin, A. D.
Bykovchenko, V. G.
Golub, N. A.
Chernyshev, E. A.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2014, 84 (02) : 280 - 284
[3] Reaction of tetrachlorogermane with thienyl- and phenylchlorosilanes in presence of aluminum chloride. Synthesis of thienylchlorogermanes
V. G. Lakhtin
M. I. Vorob’eva
E. G. Gordeev
V. N. Ushakov
A. D. Kirillin
V. G. Bykovchenko
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Russian Journal of General Chemistry, 2014, 84 : 280 - 284
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Russian Journal of General Chemistry, 2011, 81 : 1507 - 1510
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[8] NO3 chemistry of wildfire emissions: a kinetic study of the gas-phase reactions of furans with the NO3 radical
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