Efficient production of dihydroxyacetone from glycerol over a Pt/CeO2-ZrO2-Bi2O3/SBA-16 catalyst

被引：13
作者：
Choi, Pil-Gyu [1 ,2 ]
Nunotani, Naoyoshi [1 ]
Imanaka, Nobuhito [1 ]
机构：
[1] Osaka Univ, Fac Engn, Dept Appl Chem, 2-1 Yamadaoka, Suita, Osaka 5650871, Japan
[2] Natl Inst Adv Ind Sci & Technol, 2266-98 Anagahora, Nagoya, Aichi 4638560, Japan
来源：
JOURNAL OF ASIAN CERAMIC SOCIETIES | 2018年 / 6卷 / 04期
关键词：
Catalyst; selective oxidation; glycerol; dihydroxyacetone; SELECTIVE OXIDATION; PLATINUM; BISMUTH; 1,3-DIHYDROXYACETONE; CONVERSION; WATER;
D O I：
10.1080/21870764.2018.1533444
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A Pt/CeO2-ZrO2-Bi2O3/SBA-16 catalyst was prepared to realize highly selective oxidation of glycerol to produce dihydroxyacetone (DHA). An active oxygen supply from the CeO2-ZrO2-Bi2O3 promoter effectively oxidized glycerol to produce DHA under moderate conditions (i.e. at 30 degrees C without applied pressure). After a 4 h catalytic reaction using the Pt/CeO2-ZrO2-Bi2O3/SBA-16 catalyst, the DHA yield and selectivity rose to 76% and 84%, respectively.
引用
收藏
页码：368 / 373
页数：6
相关论文
共 31 条
  • [1] Catalytic conversion of biodiesel derived raw glycerol to value added products
    Bagheri, Samira
    Julkapli, Nurhidayatullaili Muhd
    Yehye, Wageeh A.
    [J]. RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2015, 41 : 113 - 127
  • [2] Nanocrystalline CeO2 in SBA-15:: Performance of Pt/CeO2/SBA-15 catalyst for water-gas-shift reaction
    Bi, Ya Dong
    Zhang, Wei
    Xu, Heng Yong
    Li, Wen Zhao
    [J]. CATALYSIS LETTERS, 2007, 119 (1-2) : 126 - 133
  • [3] Catalytic liquid phase oxidation of 1,4-dioxane over a Pt/CeO2-ZrO2-Bi2O3/SBA-16 catalyst
    Choi, Pil-Gyu
    Ohno, Takanobu
    Fukuhara, Nashito
    Masui, Toshiyuki
    Imanaka, Nobuhito
    [J]. JOURNAL OF ADVANCED CERAMICS, 2015, 4 (01) : 71 - 75
  • [4] CHEMOSELECTIVE CATALYTIC-OXIDATION OF GLYCEROL WITH AIR ON PLATINUM METALS
    GARCIA, R
    BESSON, M
    GALLEZOT, P
    [J]. APPLIED CATALYSIS A-GENERAL, 1995, 127 (1-2) : 165 - 176
  • [5] Selective oxidation of glycerol to dihydroxyacetone over a Pd-Ag catalyst
    Hirasawa, Shota
    Nakagawa, Yoshinao
    Tomishige, Keiichi
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (06) : 1150 - 1152
  • [6] Selective Oxidation of Glycerol to Dihydroxyacetone over Pt-Bi/C Catalyst: Optimization of Catalyst and Reaction Conditions
    Hu, Wenbin
    Knight, Daniel
    Lowry, Brian
    Varma, Arvind
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2010, 49 (21) : 10876 - 10882
  • [7] Significant low-temperature redox activity of Ce0.64Zr0.16Bi0.20O1.90 supported on γ-Al2O3
    Imanaka, Nobuhito
    Masui, Toshiyuki
    Koyabu, Kazuhiko
    Minami, Keisuke
    Egawa, Takamasa
    [J]. ADVANCED MATERIALS, 2007, 19 (12) : 1608 - +
  • [8] Three-dimensional visualization in powder diffraction
    Izumi, Fujio
    Momma, Koichi
    [J]. APPLIED CRYSTALLOGRAPHY XX, 2007, 130 : 15 - 20
  • [9] SELECTIVE OXIDATION OF GLYCEROL ON A PLATINUM BISMUTH CATALYST
    KIMURA, H
    TSUTO, K
    WAKISAKA, T
    KAZUMI, Y
    INAYA, Y
    [J]. APPLIED CATALYSIS A-GENERAL, 1993, 96 (02) : 217 - 228
  • [10] SELECTIVE OXIDATION OF GLYCEROL ON A PLATINUM-BISMUTH CATALYST BY USING A FIXED-BED REACTOR
    KIMURA, H
    [J]. APPLIED CATALYSIS A-GENERAL, 1993, 105 (02) : 147 - 158
1234