Cobalt diphosphonate with a new double chain structure exhibiting field-induced magnetic transition

被引：33
|
作者：
Zhang, Zai-Chao
Gao, Song
Zheng, Li Min [1 ]
机构：
[1] Nanjing Univ, Sch Chem & Chem Engn, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat & Appl, Beijing 100871, Peoples R China
来源：
DALTON TRANSACTIONS | 2007年 / 41期
关键词：
D O I：
10.1039/b709474d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A cobalt diphosphonate Co(H2O){C5H5N-CH2CH(OH)(PO3)(PO3H)} (1) has been synthesized under hydrothermal conditions. It shows a novel type of double chain structure in which one of the two CPO3 terminus caps on top of the {Co-2(mu-O)(2)} dimer while the other connects the adjacent {Co-2(mu-O)(2)} dimers into a chain. The magnetization measurements reveal that dominant antiferromagnetic interactions are mediated between the magnetic centers and the compound experiences a field-induced magnetic transition at low temperature with H-c of ca. 15 kOe at 1.8 K.
引用
收藏
页码：4681 / 4684
页数：4
相关论文
共 50 条
  • [21] The Field-Induced Magnetic Ordering Transition in TlCuCl3
    Sirker, Jesko
    Weisse, Alexander
    Sushkov, Oleg P.
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2005, 74
  • [22] Magnetic field-induced growth and self-assembly of cobalt nanocrystallites
    Niu, HL
    Chen, QW
    Zhu, HF
    Lin, YS
    Zhang, X
    JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (07) : 1803 - 1805
  • [23] Field-induced magnetic transition of Mn3GaC
    Tohoku Gakuin Univ, Tagajo, Japan
    Solid State Commun, 11 (811-814):
  • [24] Field-induced magnetic transition of Mn3GaC
    Kanomata, T
    Kikuchi, M
    Kaneko, T
    Kamishima, K
    Bartashevich, MI
    Katori, HA
    Goto, T
    SOLID STATE COMMUNICATIONS, 1997, 101 (11) : 811 - 814
  • [25] Magnetic field-induced Freedericksz transition in a chiral liquid crystal
    Missaoui, Amine
    Susser, Adam L.
    Aharoni, Hillel
    Rosenblatt, Charles
    APPLIED PHYSICS LETTERS, 2023, 122 (13)
  • [26] MAGNETIC FIELD-INDUCED TRANSITION IN Y1-XGDX
    GOTAAS, JA
    RHYNE, JJ
    WENGER, LE
    MYDOSH, JA
    JOURNAL OF APPLIED PHYSICS, 1987, 61 (08) : 3415 - 3417
  • [27] Supramolecular lanthanide metallogrids exhibiting field-induced single-ion magnetic behavior
    Wu, Shu-Qi
    Xie, Qi-Wei
    An, Guang-Yu
    Chen, Xi
    Liu, Cai-Ming
    Cui, Ai-Li
    Kou, Hui-Zhong
    DALTON TRANSACTIONS, 2013, 42 (13) : 4369 - 4372
  • [28] Magnetic field-induced magnetic transition in Gd2Al compound
    Li, Xingguo
    Journal of Magnetism and Magnetic Materials, 1999, 205 (02): : 307 - 310
  • [29] MAGNETIC FIELD-INDUCED METAL-INSULATOR-TRANSITION IN DILUTED MAGNETIC SEMICONDUCTORS
    JAROSZYNSKI, J
    DIETL, T
    PHYSICA B, 1992, 177 (1-4): : 469 - 475
  • [30] Magnetic field-induced magnetic transition in Gd2Al compound
    Li, XG
    JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 1999, 205 (2-3) : 307 - 310
12345