The Improvement of Electro-Optical Properties of Polymer-Dispersed Liquid Crystals using Copolymer Macroinitiator with Different Glass Transition Temperature

被引:8
|
作者
Du, Xin [1 ]
Yan, Bin [1 ]
Yao, Jiali [1 ]
Chen, Shu [1 ]
Li, Minke [1 ]
Wang, Yinghan [1 ]
机构
[1] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China
基金
中国国家自然科学基金;
关键词
copolymer; glass transition temperature; living radical polymerization; optics; PDLC; RAFT; MOLECULAR-WEIGHT; PERFORMANCE; MATRIX; FILMS;
D O I
10.1002/pola.24367
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this article, copolymer macroinitiators prepared with styrene and iso-octyl acrylate by reversible additional-fragmental chain transfer polymerization were used to prepare polymer-dispersed liquid crystals (PDLCs) with methyl acrylate. The electro-optical properties of the PDLCs were investigated. The results showed that the glass transition temperature (T-g) of the macroinitiator has a great influence on the memory effect of the resulting PDLCs. Low driving voltage and low memory effect PDLCs could easily be obtained with copolymer macroinitiators. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 5557-5561, 2010
引用
收藏
页码:5557 / 5561
页数:5
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