Single-Crystal-to-Single-Crystal Anion Exchange in a Gadolinium MOF: Incorporation of POMs and [AuCl4]-

被引：6

作者：

Lopez-Cabrelles, Javier ^{[1
]}

Minguez Espallargas, Guillermo ^{[1
]}

Coronado, Eugenio ^{[1
]}

机构：

[1] Univ Valencia, Inst Ciencia Mol ICMol, C Catedrat Jose Beltran 2, Paterna 46980, Spain

来源：

POLYMERS | 2016年 / 8卷 / 05期

关键词：

MOFs; anion exchange; polyoxometalates; METAL-ORGANIC FRAMEWORKS; INFINITE POLYMERIC FRAMEWORKS; COORDINATION POLYMER; HYDROGEN STORAGE; POROUS MATERIALS; DESIGN; FUNCTIONALIZATION; TRANSFORMATION; ADSORPTION; CATALYSTS;

D O I：

10.3390/polym8050171

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The encapsulation of functional molecules inside porous coordination polymers (also known as metal-organic frameworks, MOFs) has become of great interest in recent years at the field of multifunctional materials. In this article, we present a study of the effects of size and charge in the anion exchange process of a Gd based MOF, involving molecular species like polyoxometalates (POMs), and [AuCl4](-). This post-synthetic modification has been characterized by IR, EDAX, and single crystal diffraction, which have provided unequivocal evidence of the location of the anion molecules in the framework.

引用

页数：14

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