Pyrenediones as versatile photocatalysts for oxygenation reactions with in situ generation of hydrogen peroxide under visible light

被引：35

作者：

Zhang, Yuannian ^{[1
]}

Yang, Xin ^{[1
]}

Tang, Haidi ^{[2
]}

Liang, Dong ^{[1
]}

Wu, Jie ^{[2
]}

Huang, Dejian ^{[1
]}

机构：

[1] Natl Univ Singapore, Dept Chem, Food Sci & Technol Program, Singapore 117543, Singapore

[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

GREEN CHEMISTRY | 2020年 / 22卷 / 01期

关键词：

MOLECULAR-OXYGEN; GEM-DIHYDROPEROXIDES; EFFICIENT SYNTHESIS; ANTHRAQUINONE; 2-PROPANOL; ACTIVATION; OXIDATION; ACID;

D O I：

10.1039/c9gc03152a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pyrenediones (PYDs) are efficient photocatalysts for three oxygenation reactions: epoxidation of electron deficient olefins, oxidative hydroxylation of organoborons, and oxidation of sulfides via in situ generation of H2O2 under visible light irradiation, using oxygen as a terminal oxidant and IPA as a solvent and a hydrogen donor.

引用

页码：22 / 27

页数：6

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