Pyrenediones as versatile photocatalysts for oxygenation reactions with in situ generation of hydrogen peroxide under visible light

被引：35
|
作者：
Zhang, Yuannian [1 ]
Yang, Xin [1 ]
Tang, Haidi [2 ]
Liang, Dong [1 ]
Wu, Jie [2 ]
Huang, Dejian [1 ]
机构：
[1] Natl Univ Singapore, Dept Chem, Food Sci & Technol Program, Singapore 117543, Singapore
[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源：
GREEN CHEMISTRY | 2020年 / 22卷 / 01期
关键词：
MOLECULAR-OXYGEN; GEM-DIHYDROPEROXIDES; EFFICIENT SYNTHESIS; ANTHRAQUINONE; 2-PROPANOL; ACTIVATION; OXIDATION; ACID;
D O I：
10.1039/c9gc03152a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pyrenediones (PYDs) are efficient photocatalysts for three oxygenation reactions: epoxidation of electron deficient olefins, oxidative hydroxylation of organoborons, and oxidation of sulfides via in situ generation of H2O2 under visible light irradiation, using oxygen as a terminal oxidant and IPA as a solvent and a hydrogen donor.
引用
收藏
页码：22 / 27
页数：6
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