[Ru(CO)(CH3CO2)(tpa)]ClO4•C6H5CH3 (tpa = tris(2-pyridylmethyl)amine), the first ruthenium carbonyl complex of tpa

被引：4
|
作者：
Xu, L [1 ]
Sasaki, Y [1 ]
机构：
[1] Hokkaido Univ, Grad Sch Sci, Div Chem, Kita Ku, Sapporo, Hokkaido 0600810, Japan
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 1999年 / 2卷 / 04期
关键词：
ruthenium complexes; polypyridyl complexes; carboxylate complexes; carbonyl complexes;
D O I：
10.1016/S1387-7003(99)00026-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of dodecacarbonyltriruthenium with tris(2-pyridylmethyl) ammonium perchlorate (tpa . 3HClO(4)), in the presence of acetic acid, afforded a new ruthenium complex of tpa, [Ru(CO)(CH3CO2)(tpa)]ClO4. C6H5CH3 (1). Compound 1 has been characterized by X-ray structural analysis, IR and H-1 NMR spectra. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：121 / 123
页数：3
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