Zirconium bistriazolylpyridine phosphonate materials for efficient, selective An(iii)/Ln(iii) separations

被引：15

作者：

Veliscek-Carolan, Jessica ^{[1
]}

Rawal, Aditya ^{[2
]}

机构：

[1] ANSTO, Locked Bag 2001, Kirrawee Dc, NSW 2232, Australia

[2] Univ New South Wales, Mark Wainwright Analyt Ctr, Kensington, NSW 2052, Australia

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 08期

关键词：

STABILITY; LANTHANIDES; EXTRACTION; ACTINIDES; AM(III); ACIDS; NMR;

D O I：

10.1039/c8cc07892k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Direct synthesis of ZrCl4 and bistriazolylpyridine phosphonate has produced novel sorbent materials that, for the first time, demonstrate selective extraction of Am(iii) in the presence of excess Eu(iii). Further, the high ligand content of these materials affords them high extraction efficiencies.

引用

页码：1168 / 1171

页数：4

共 22 条

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