New numerical and experimental results on the transition between regular and Mach reflections of steady shock waves are presented. The influence of flow three-dimensionality on transition between steady regular and Mach reflection has been studied in detail both numerically and experimentally. Characteristic features of 3D shock wave configuration, such as peripheral Mach reflection, non-monotonous Mach stem variation in transverse direction, the existence of combined Mach-regular-peripheral Mach shock wave configuration, have been found in the numerical simulations. The application of laser sheet imaging technique in streamwise direction allowed us to confirm all the details of shock wave configuration in the experiments. Close agreement of the numerical and experimental data on Mach stem heights is shown.