Freezing conformation of polychloronitrophenyl N-substituted morpholines studied by DNMR and X-ray crystal structure

被引：0
|
作者：
Zou, XZ
Kuma, H
Ibata, T
Suga, H
机构：
[1] E China Normal Univ, Dept Chem, Shanghai 200062, Peoples R China
[2] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 560, Japan
[3] Shinshu Univ, Fac Engn, Dept Mat Engn, Nagano 3808553, Japan
来源：
JOURNAL OF CHEMICAL RESEARCH-S | 2001年 / 07期
关键词：
conformation of polychloronitrophenyl N-substituted morpholines;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The acceleration of SNAr reaction of aromatic halides has been studied with various amines under high pressure. Compounds having high steric hindrance as 2-morpholino-substituted polychloro-1-nitrobenzenes were obtained. These showed different behaviours of methylene protons of morphlino ring at room temperature apparently related to the higher steric hindrance. So these compounds were investigated using dynamic H-1 NMR and single crystal X-ray crystallography.
引用
收藏
页码：265 / 265
页数：1
相关论文
共 50 条
  • [1] X-ray crystal structure and conformational flexibility study of a N-substituted 2,6-diphenylpiperidine derivative
    N. Sampath
    Journal of Structural Chemistry, 2017, 58 : 804 - 808
  • [2] X-ray crystal structure and conformational flexibility study of a N-substituted 2,6-diphenylpiperidine derivative
    Sampath, N.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 58 (04) : 804 - 808
  • [3] X-ray crystal structure of mercury substituted azurin
    Zampino, Anthony P.
    Masters, Francesca M.
    Panzner, Matthew J.
    Bladholm, Erika L.
    Berry, Steven M.
    Ziegler, Chris J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2013, 246
  • [4] CONFORMATION OF 3-SUBSTITUTED PURINE NUCLEOSIDE STUDIED BY X-RAY CRYSTALLOGRAPHY AND THEORETICAL CALCULATIONS
    YAMAGATA, Y
    KATO, M
    FUJII, S
    AOYAGI, M
    MINAKAWA, N
    MATSUDA, A
    NUCLEOSIDES & NUCLEOTIDES, 1994, 13 (6-7): : 1327 - 1335
  • [5] The reaction of phthalidylidene dichloride with primary amines. Synthesis and X-ray molecular structure of N-substituted phthalisoimides
    Guirado, A
    Zapata, A
    de Arellano, MCR
    TETRAHEDRON, 1997, 53 (14) : 5305 - 5324
  • [6] Crystal Structure and Phototransistor Behavior of N-Substituted Heptacence
    Wu, Yuechao
    Yin, Zongyou
    Xiao, Jinchong
    Liu, Yi
    Wei, Fengxia
    Tan, Ke Jie
    Kloc, Christian
    Huang, Ling
    Yan, Qingyu
    Hu, Fangzhong
    Zhang, Hua
    Zhang, Qichun
    ACS APPLIED MATERIALS & INTERFACES, 2012, 4 (04) : 1883 - 1886
  • [7] Automated crystal harvesting, freezing and X-ray diffraction
    Khajepour, M. Y. Heidari
    Ferrer, Jean-Luc
    Vernede, Xavier
    Berzin, Christophe
    Terrien, Maxime
    Joly, Jacques
    Mazel, Pierre
    Rogues, Pierrick
    Bouis, Florian
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C280 - C280
  • [8] Layer structure of antiferroelectric liquid crystal MHPOBC studied by X-ray diffraction
    Suzuki, Atsushi, 1600, (29):
  • [9] Synthesis of N-polyfluorinated alkyl derivatives of uracil and 5-substituted uracils -: X-ray structure of a mono N-substituted 5-trifluoromethyluracil
    Gupta, OD
    Twamley, B
    Kirchmeier, RL
    Shreeve, JM
    JOURNAL OF FLUORINE CHEMISTRY, 2000, 106 (02) : 199 - 204
  • [10] Synthesis, X-ray crystal structure, DNA/protein binding and DNA cleavage studies of novel copper(II) complexes of N-substituted isatin thiosemicarbazone ligands
    Muralisankar, Mathiyan
    Bhuvanesh, Nattamai S. P.
    Sreekanth, Anandaram
    NEW JOURNAL OF CHEMISTRY, 2016, 40 (03) : 2661 - 2679
12345