Studying the role of polysiloxane additives and nano-SiO2 on the mechanical properties of a typical acrylic/melamine clearcoat

被引：22

作者：

Ramezanzadeh, B. ^{[1
,2
]}

Moradian, S. ^{[1
]}

Tahmasebi, N. ^{[3
]}

Khosravi, A. ^{[1
]}

机构：

[1] Amirkabir Univ Technol, Dept Polymer Engn & Color Technol, Tehran, Iran

[2] Inst Color Sci & Technol, Dept Surface Coatings & Corros, Tehran, Iran

[3] Islamic Azad Univ, Mahshahr Branch, Dept Polymer Engn, Mahshahr 63519, Iran

来源：

PROGRESS IN ORGANIC COATINGS | 2011年 / 72卷 / 04期

关键词：

Polysiloxan additives; Nano-SiO2; Mechanical properties; Nano-indentation; ATR-FTIR; SCRATCH RESISTANCE; COATINGS; SURFACE; PERFORMANCE; PARTICLES; BEHAVIOR; MODELS;

D O I：

10.1016/j.porgcoat.2011.07.003

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Effects of conventional polysiloxane additives and nano-SiO2 on the mechanical properties of an automotive acrylic/melamine clearcoat (CC) are studied. Clearcoats formulations were prepared by addition of different concentrations of polysioloxane additives (with different modifications) and hydrophobic nano-SiO2 particles. Attenuated Total Reflection-Fourier Transform Infrared (ATR-FTIR) and atomic force microscope (AFM) were utilized to evaluate the effects of nano-SiO2 and polysiloxane additives on the surface properties of the CCs. The mechanical properties of the surface and the bulk of the CCs were studied by nano-indentation and tensile tests, respectively. Results showed that polysiloxane additives can mostly affect the mechanical properties of the surface of the CC. Additives with shorter side chains and therefore higher surface activity caused higher changes on the surface properties the CC. Unlike conventional polysiloxane additives, the nano-SiO2 particles mainly influenced the mechanical properties of the bulk of the CC. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：621 / 631

页数：11

共 50 条

[21] Enhanced mechanical properties and thermal stability of cellulose insulation paper achieved by doping with melamine-grafted nano-SiO2
Chao Tang
Song Zhang
Xiaobo Wang
Jian Hao
Cellulose, 2018, 25 : 3619 - 3633
[22] Enhanced mechanical properties and thermal stability of cellulose insulation paper achieved by doping with melamine-grafted nano-SiO2
Tang, Chao
Zhang, Song
Wang, Xiaobo
Hao, Jian
CELLULOSE, 2018, 25 (06) : 3619 - 3633
[23] Surface treatment mechanism of nano-SiO2 and the properties of PP/nano-SiO2 composite materials
Wei Wu
Manfred H. Wagner
Zhongde Xu
Colloid and Polymer Science, 2003, 281 : 550 - 555
[24] Hybrid polysiloxane/polyacrylate/nano-SiO2 emulsion for waterborne polyurethane coatings
Jiang, Weibin
Dai, Anqi
Zhou, Tao
Xie, Huasheng
POLYMER TESTING, 2019, 80
[25] The dynamic mechanical properties of nano-SiO2 concrete after freezing and thawing
Shan, Tong
International Journal of Microstructure and Materials Properties, 2024, 17 (04) : 322 - 332
[26] Effect of nano-SiO2 and lime on characteristics and mechanical properties of coastal clay
Shang, Wentao
Liu, Zhong
Gao, Yuqin
FUNCTIONAL MATERIALS, 2019, 26 (01): : 216 - 220
[27] Studies on dynamic mechanical and rheological properties of LLDPE/nano-SiO2 composites
Huang, YQ
Zhang, YQ
Hua, YQ
JOURNAL OF MATERIALS SCIENCE LETTERS, 2003, 22 (14) : 997 - 998
[28] Research on Thermal Aging and Mechanical Properties of the Nano-SiO2/Epoxy Adhesive
Zhang, Peihong
Cheng, Sheng
Shao, Qi
2015 IEEE 11TH INTERNATIONAL CONFERENCE ON THE PROPERTIES AND APPLICATIONS OF DIELECTRIC MATERIALS, 2015, : 556 - 559
[29] Mechanical and thermal properties of nano-SiO2/PA66 composites
Hu, Xiuchi
Xu, Xiangmin
Zhang, Yudong
Li, Binjie
Zhang, Zhijun
ADVANCED RESEARCH ON INFORMATION SCIENCE, AUTOMATION AND MATERIAL SYSTEM, PTS 1-6, 2011, 219-220 : 228 - +
[30] INFLUENCE OF NANO-SiO2 AND CARBON FIBERS ON THE MECHANICAL PROPERTIES OF POM COMPOSITES
Fu, Y. F.
Hu, K.
Li, J.
Sun, Z. H. Y.
Zhang, F. Q.
Chen, D. M.
MECHANICS OF COMPOSITE MATERIALS, 2012, 47 (06) : 659 - 662

← 1 2 3 4 5 →