N-(1-Oxy-2-picolyl)oxalamic Acid as an Efficient Ligand for Copper-Catalyzed Amination of Aryl Iodides at Room Temperature

被引：23

作者：

Wang, Yongbin ^{[1
]}

Ling, Jing ^{[1
]}

Zhang, Yu ^{[2
]}

Zhang, Ao ^{[3
]}

Yao, Qizheng ^{[1
]}

机构：

[1] China Pharmaceut Univ, Sch Pharm, Nanjing 210009, Jiangsu, Peoples R China

[2] Allist Pharmaceut Inc, Shanghai, Peoples R China

[3] Chinese Acad Sci, Shanghai Inst Mat Med, Shanghai 200000, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 2015卷 / 19期

关键词：

Synthetic methods; Ligand design; N; O ligands; Copper; Amination; C-N; ALIPHATIC-AMINES; AQUEOUS AMMONIA; MAGNETIC-PROPERTIES; COUPLING REACTIONS; ARYLATION; COMPLEXES; HALIDES; OXIDES; IMIDAZOLES;

D O I：

10.1002/ejoc.201500279

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N-(1-Oxy-pyridin-2-ylmethyl)oxalamic acid was identified as efficient ligand for CuI-catalyzed amination of aryl halides at room temperature. In our catalytic system, N-arylation of cyclic secondary amines, primary amines, amino acids, and ammonia proceeded with moderate to excellent yields and high functional group tolerance.

引用

页码：4153 / 4161

页数：9

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