Rapid preparation of noble metal nanocrystals via facile coreduction with graphene oxide and their enhanced catalytic properties

被引：43

作者：

Xiang, Guolei ^{[1
]}

He, Jie ^{[1
]}

Li, Tianyang ^{[1
]}

Zhuang, Jing ^{[1
]}

Wang, Xun ^{[1
]}

机构：

[1] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China

来源：

NANOSCALE | 2011年 / 3卷 / 09期

关键词：

GRAPHITE OXIDE; PALLADIUM NANOPARTICLES; COUPLING REACTION; OXYGEN REDUCTION; NANOSTRUCTURES; COMPOSITE; SHEETS; GROWTH; DERIVATIVES; NANOSHEETS;

D O I：

10.1039/c1nr10439j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We present the facile preparation results of noble metal nanostructures induced by graphene via rapid coreduction by Ti3+ at room temperature. Such a reduction of graphene oxide (GO) can be readily performed in solutions or on various substrates within seconds. High quality noble metal nanocrystals can be prepared by using graphene as the controlling agent at room temperature, including Rh, Au and Rh-Pt nanodendrites and Pd nanoparticles, showing the roles of graphene on tuning the growth behaviors of nanostructures. These surface clean Pd nanoparticles show high catalytic activity and selectivity in Suzuki and Heck coupling reactions.

引用

页码：3737 / 3742

页数：6

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