Rhodium(III)-Catalyzed ortho-Arylation of Anilides with Aryl Halides

被引:41
作者
Haridharan, Radhakrishnan [1 ]
Muralirajan, Krishnamoorthy [1 ]
Cheng, Chien-Hong [1 ]
机构
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan
关键词
C-C coupling; C-H activation; iodobenzene; N-phenylpivalamide; rhodium; homogeneous catalysis; C-H ACTIVATION; ONE-POT SYNTHESIS; CATALYZED ORTHO-ARYLATION; BOND ACTIVATION; N-METHOXYBENZAMIDES; INTERNAL ALKYNES; BORONIC ACIDS; COUPLING REACTIONS; EASY ROUTE; RHODIUM;
D O I
10.1002/adsc.201400798
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
An efficient o-arylation of pivalamides by aryl iodides via rhodium(III)-catalyzed C-H activation is demonstrated for the first time. Further, the biaryl products can be converted effectively into biologically active phenanthridine and phenanthridinone derivative.
引用
收藏
页码:366 / 370
页数:5
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