Activation of olefins with low-valent gallium compounds under ambient conditions

被引：41

作者：

Caputo, Christine A. ^{[1
]}

Zhu, Zhongliang ^{[1
]}

Brown, Zachary D. ^{[1
]}

Fettinger, James C. ^{[1
]}

Power, Philip P. ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 26期

基金：

加拿大自然科学与工程研究理事会;

关键词：

SILICON DOUBLE-BOND; DISILYNE RSISIR R; BIRADICAL INTERMEDIATE; MOLECULAR-STRUCTURE; STABLE COMPOUND; GA-GA; ALKYNE; ANALOG; TETRAMESITYLDISILENE; DIMETALLENES;

D O I：

10.1039/c1cc11676b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of Ar'GaGaAr' (Ar' = C(6)H(3)-2,6-(C(6)H(3)-2,6- (i)Pr(2))(2)) with alkenes revealed the addition of two olefins per Ar'GaGaAr' under ambient conditions for ethylene, propene, 1-hexene and styrene but no reactions with more hindered or cyclic olefins.

引用

收藏

页码：7506 / 7508

页数：3

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