Crystallization and Second Harmonic Generation of Lithium Niobium Silicate Glass Ceramics

被引：20

作者：

Vigouroux, Helene ^{[1
,2
]}

Fargin, Evelyne ^{[1
]}

Fargues, Alexandre ^{[1
]}

Le Garrec, Bruno ^{[2
]}

Dussauze, Marc ^{[3
]}

Rodriguez, Vincent ^{[3
]}

Adamietz, Frederic ^{[3
]}

Mountrichas, Grigoris ^{[1
,3
,5
]}

Kamitsos, Efstratios ^{[5
]}

Lotarev, Sergey ^{[4
]}

Sigaev, Vladimir ^{[4
]}

机构：

[1] Univ Bordeaux, Inst Chim Mat Condensee Bordeaux, CNRS, F-33608 Pessac, France

[2] CEA, CESTA, F-33114 Le Barp, France

[3] Univ Bordeaux, CNRS, Inst Mol Sci, UMR 5255, F-33405 Talence, France

[4] Mendeleev Univ Chem Technol Russia, Opt Glass Ctr, Moscow 125047, Russia

[5] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece

来源：

JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2011年 / 94卷 / 07期

关键词：

DIFFERENTIAL THERMAL-ANALYSIS; 2ND-ORDER OPTICAL NONLINEARITY; SUBSEQUENT HEAT-TREATMENT; BOND-ORBITAL THEORY; ORIENTED CRYSTALLIZATION; ELECTRIC-FIELD; ISOTHERMAL CRYSTALLIZATION; IONIC-CRYSTALS; NUCLEATION; NIOBATE;

D O I：

10.1111/j.1551-2916.2011.04416.x

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

An extended study of lithium niobium silicate glass crystallization with the molar composition 35Li(2)O-25Nb(2)O(5)-40SiO(2) is presented. Depending on the heat treatments, both surface and/or bulk crystallizations of the LiNbO3 crystalline phase were observed. X-ray diffraction together with second harmonic generation (SHG) measurements have revealed a net preferred orientation of the ferroelectric crystallites at the surface which is quite different in the bulk. A striking and promising SHG response estimated to be five times larger than a-quartz has been observed in the bulk.

引用

页码：2080 / 2086

页数：7

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