Palladium/tetraphosphine catalyzed suzuki cross-coupling of heteroarylboronic acids with aryl halides

被引：23
|
作者：
Kondolff, Isabelle [2 ,3 ]
Doucet, Henri [1 ]
Santelli, Maurice [2 ,3 ]
机构：
[1] Univ Rennes Catalyse & Organomet, CNRS, Inst Sci Chim Rennes, UMR 6226, F-35042 Rennes, France
[2] Univ Aix Marseille 3, Synth Organ Lab, Fac Sci St Jerome, Univ Aix Marseille 3 Chirotechnol Catalyse & Bioc, F-13397 Marseille 20, France
[3] Univ Aix Marseille 3, CNRS, UMR 6180, F-13397 Marseille 20, France
来源：
JOURNAL OF HETEROCYCLIC CHEMISTRY | 2008年 / 45卷 / 01期
关键词：
D O I：
10.1002/jhet.5570450109
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
cis,cis,cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl(C3H5)](2) efficiently catalyses the Suzuki reaction of heteroarylboronic acids with aryl bromides and also the coupling of arylboronic acids with heteroaryl bromides. The coupling of thiophene- orbenzothiopheneboronic acids, furan- or benzofuranboronic acids and 3-pyridineboronic acid with a variety of aryl bromides gave the corresponding coupling products in good yields. However, in most cases, better results in terms of ratio substrate/catalyst were obtained for the reverse reaction using heteroaryl bromides with arylboronic acids.
引用
收藏
页码：109 / 118
页数：10
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