Palladium/tetraphosphine catalyzed suzuki cross-coupling of heteroarylboronic acids with aryl halides

被引：23

作者：

Kondolff, Isabelle ^{[2
,3
]}

Doucet, Henri ^{[1
]}

Santelli, Maurice ^{[2
,3
]}

机构：

[1] Univ Rennes Catalyse & Organomet, CNRS, Inst Sci Chim Rennes, UMR 6226, F-35042 Rennes, France

[2] Univ Aix Marseille 3, Synth Organ Lab, Fac Sci St Jerome, Univ Aix Marseille 3 Chirotechnol Catalyse & Bioc, F-13397 Marseille 20, France

[3] Univ Aix Marseille 3, CNRS, UMR 6180, F-13397 Marseille 20, France

来源：

JOURNAL OF HETEROCYCLIC CHEMISTRY | 2008年 / 45卷 / 01期

关键词：

D O I：

10.1002/jhet.5570450109

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

cis,cis,cis-1,2,3,4-Tetrakis(diphenylphosphinomethyl)cyclopentane/[PdCl(C3H5)](2) efficiently catalyses the Suzuki reaction of heteroarylboronic acids with aryl bromides and also the coupling of arylboronic acids with heteroaryl bromides. The coupling of thiophene- orbenzothiopheneboronic acids, furan- or benzofuranboronic acids and 3-pyridineboronic acid with a variety of aryl bromides gave the corresponding coupling products in good yields. However, in most cases, better results in terms of ratio substrate/catalyst were obtained for the reverse reaction using heteroaryl bromides with arylboronic acids.

引用

页码：109 / 118

页数：10

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