An N,N′-diethylformamide solvent-induced conversion cascade within a metal-organic framework single crystal

被引：11
作者：
Chen, Jing [1 ]
Chao, Meng-Yao [1 ]
Liu, Yan [1 ]
Xu, Bo-Wei [1 ]
Zhang, Wen-Hua [1 ]
Young, David J. [2 ]
机构：
[1] Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China
[2] Charles Darwin Univ, Coll Engn Informat Technol & Environm, Darwin, NT 0909, Australia
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 44期
基金：
中国国家自然科学基金;
关键词：
CRYSTALLOGRAPHIC VISUALIZATION; METALORGANIC FRAMEWORKS; LIGAND-EXCHANGE; CO2; ADSORPTION; BEHAVIOR; REARRANGEMENTS; LUMINESCENCE; SORPTION; BEARING;
D O I：
10.1039/d0cc02420a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Crystals of a two-dimensional (2D) metal-organic framework (MOF) [Cd-3(BTB)(2)(DEF)(4)]center dot 2(DEF) 0.5 (1; BTB = benzene-1,3,5-tribenzolate; DEF = N,N'-diethylformamide) immersed in a solution of trans1,2-bis(4-pyridyl)ethylene (BPEE) yields an interpenetrated threedimensional (3D) MOF of [Cd-3(BTB)(2)(BPEE)(H2O)(2)]center dot(BPEE)center dot xSol (2). Crystals of MOF 2, in turn, undergo a cascade conversion when immersed in DEF, yielding [Cd-3(BTB)(2)(BPEE)(1.8)(DEF)(0.9)(H2O)(0.8)]center dot xSol (3a) over 100 seconds and [Cd-3(BTB)(2)(BPEE)(2)(DEF)(2)]center dot xSol (4) after one hour, before finally shuttling back to MOF 1 after six hours.
引用
收藏
页码：5877 / 5880
页数：4
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