Munronoids A-J, ten new limonoids from Munronia unifoliolata Oliv

被引：25
作者：
Ge, Yong-Hui [1 ,2 ,3 ]
Zhang, Jian-Xin [1 ,2 ]
Mu, Su-Zhen [1 ,2 ]
Chen, Yan [1 ,2 ]
Yang, Fu-Mei [1 ,2 ]
Lu, Yang [4 ]
Hao, Xiao-Jiang [1 ,2 ]
机构：
[1] Key Lab Chem Nat Prod Guizhou Prov, Guiyang 550002, Peoples R China
[2] Chinese Acad Sci, Guiyang 550002, Peoples R China
[3] Guizhou Univ, Ctr Res & Dev Fine Chem, Guiyang 550002, Peoples R China
[4] Chinese Acad Med Sci, Inst Mat Med, Beijing 100050, Peoples R China
来源：
TETRAHEDRON | 2012年 / 68卷 / 02期
关键词：
Munronoids; Limonoids; Munronia unifoliolata Oliv; Insecticidal activity; Anti-TMV activity; CIPADESSA-CINERASCENS; TETRANORTRITERPENOIDS; MELIACEAE; MAHOGANY;
D O I：
10.1016/j.tet.2011.11.003
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Ten new limonoids, named munronoids A-J (1-10), were isolated from Munronia unifoliolata Oliv. These limonoids involved in the skeletons of peieurianin, evodulone, euphane, and havanensin-types of limonoids, and their structures were established on the basis of spectroscopic data and X-ray crystallographic method. Compounds 1 and 2 were rollout of the conjugated Delta(8.30) and Delta(14.15) double bonds in peieurianin-type, 3-6 featuring a gamma-lactone ring instead of the beta-substituted furan ring were found in the evodulone-type for the first time. The insecticidal and anti-TMV activities of compounds 1-10 were also evaluated. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：566 / 572
页数：7
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