Synthesis, infrared spectra and thermal studies of Zn(II), Cd(II) and Hg(II) complexes with 2-aminobenzaldehyde phenylhydrazone "nitrin" ligand

被引：12

作者：

Refat, Moamen S. ^{[1
]}

Ibrahim, Asmaa A. ^{[2
]}

机构：

[1] Suez Canal Univ, Fac Educ, Dept Chem, Port Said, Egypt

[2] Fac Sci, Dept Chem, Aswan, Egypt

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2008年 / 70卷 / 01期

关键词：

nitrin; transition metals; thermal analysis; biological screening;

D O I：

10.1016/j.saa.2007.05.065

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The, nitrin, 2-aminobenzaldehyde phenylhydrazone (2ABPH) was synthesis by refluxing 2-nitrobenzaldehyde with phenylhydrazine in ethanolic solvent. Three transition metal (II) complexes of 2ABPH have been prepared. Elemental analysis, molar conductivity, IR, UV, H-1 NMR, and mass spectra, as well as TG/DTG have been used to characterize these complexes. The complexes have the general formula [M(2Al(3)PH)(2)]Cl-2 center dot nH(2)O, where M=Zn, Cd, and Hg and n=4, 2 and 0 for Zn(II), Cd(II) and Hg(II), respectively. The ligand and its complexes have been studied for their possible biological activity including antibacterial and anti fungal activity. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：234 / 242

页数：9

共 21 条

[1] Supramolecular architecture of cadmium(II)-terephthalate complexes having a tridentate or tetradentate Schiff base as blocking coligand [J].

Banerjee, S ;

Lassahn, PG ;

Janiak, C ;

Ghosh, A .

POLYHEDRON, 2005, 24 (18) :2963-2971

[2] REDUCTIVE ACYLATION OF SCHIFF BASES USING TRIMETHYLAMINE BORANE .4. [J].

BILLMAN, JH ;

MCDOWELL, JW .

JOURNAL OF ORGANIC CHEMISTRY, 1962, 27 (07) :2640-&

[3] Interaction of copper(II) complex of compartmental Schiff base ligand N,N′-bis(3-hydroxysalicylidene)ethylenediamine with bovine serum albumin [J].

Boghaei, Davar M. ;

Farvid, Shokouh S. ;

Gharagozlou, Mehmaz .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2007, 66 (03) :650-655

[4] Metal-assisted syntheses and NMR characterization of square-planar Pd(II) and Pt(II) complexes with tridentate nitrogen-donor chelate ligands [J].

Bortoluzzi, Marco ;

Paolucci, Gino ;

Pitteri, Bruno ;

Vavasori, Andrea .

INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (12) :1301-1303

[5] KINETIC PARAMETERS FROM THERMOGRAVIMETRIC DATA [J].

COATS, AW ;

REDFERN, JP .

NATURE, 1964, 201 (491) :68-&

[6] Copper(II) complexes with tridentate N-(benzoyl)-N′-(salicylidine)-hydrazine and monodentate N-heterocycles:: Investigations of intermolecular interactions in the solid state [J].

Das, S ;

Pal, S .

JOURNAL OF MOLECULAR STRUCTURE, 2005, 753 (1-3) :68-79

[7] Two new copper(II) complexes with the shortest (N-N) diazine based rigid ligand: Example of unusual tridentate coordination mode [J].

Karmakar, Ruma ;

Choudhury, Chirantan Roy ;

Batten, Stuart R. ;

Mitra, Samiran .

JOURNAL OF MOLECULAR STRUCTURE, 2007, 826 (2-3) :75-81

[8] Synthesis and characterization of Mg(II), Mn(II), Zn(II) and Cd(II) complexes with a new heptaaza Schiff base pendant-armed macrocycle:: X-ray crystal structure, NMR and computational study [J].

Khanmohammadi, Hamid ;

Amani, Saeid ;

Lang, Heinrich ;

Rueeffer, Tobias .

INORGANICA CHIMICA ACTA, 2007, 360 (02) :579-587

[9]

KNOPFER, 1910, MONATSH, V31, P97

[10] LIQUID-CRYSTAL DERIVATIVES OF TRANSITION METALS(1) - TETRACOORDINATED COPPER(11) COMPLEXES DERIVED FROM SCHIFFS BASES [J].

MARCOS, M ;

ROMERO, P ;

SERRANO, JL ;

BUENO, C ;

CABEZA, JA ;

ORO, LA .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1989, 167 :123-134

← 1 2 3 →