Effects of specific interactions on the anisotropy of crystal structure distortion of [Co(NH3)5NO2]Cl2 under hydrostatic pressure

被引：2

作者：

Boldyreva, EV ^{[1
]}

Naumov, DY

Ahsbahs, H

机构：

[1] Russian Acad Sci, Inst Solid State Chem, Siberina Branch, Novosibirsk, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

[3] Univ Marburg, D-35032 Marburg, Germany

来源：

JOURNAL OF STRUCTURAL CHEMISTRY | 1998年 / 39卷 / 03期

关键词：

D O I：

10.1007/BF02873641

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Using some special experimental techniques for anisotropic refinement of the crystal structure of [Co(NH3)(5)NO2]Cl-2 at high pressures gave results with an accuracy comparable to that obtained in normal conditions. The anisotropy of lattice compression under pressure is determined by specific interactions in crystals, in particular, by NH-CI and NH-O hydrogen bonds. The anisotropy of compression at increased pressure is qualitatively distinct from that caused by lowered temperature for the same structure. This difference is also due to specific interactions (hydrogen bonds) in the structure.

引用

页码：350 / 361

页数：12

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