Photochemically Driven Addition of Iminyl Radicals to Alkynyl Fischer Carbene Complexes

被引：10
|
作者：
Blanco-Lomas, Marina [1 ]
Caballero, Alegria [1 ]
Campos, Pedro J. [1 ]
Gonzalez, Hector F. [1 ]
Lopez-Sola, Susana [1 ]
Rivado-Casas, Laura [1 ]
Rodriguez, Miguel A. [1 ]
Sampedro, Diego [1 ]
机构：
[1] Univ La Rioja, Dept Quim, Grp Sintesis Quim Rioja, Unidad Asociada CSIC, E-26006 Logrono, Spain
来源：
ORGANOMETALLICS | 2011年 / 30卷 / 13期
关键词：
INSERTION REACTION; CHEMISTRY; INVENTION;
D O I：
10.1021/om200438y
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Nitrogen-centered radicals, generated by the action of UV light, are capable of reacting with alkynyl Fischer carbene complexes in two ways, 1,2- and 1,4-addition. Our results constitute the first reported example of a photochemically driven reaction of this kind.
引用
收藏
页码：3677 / 3682
页数：6
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