A ferric molybdenum phosphate with a tunnel:: hydrothermal synthesis and structure of (NH3CH2CH2NH3)2•(NH3CH2CH2NH2)3•Na•[Fe2Mo12O30(PO4)(HPO4)4(H2PO4)3]•7H2O

被引：44
作者：
Xu, L
Sun, YQ
Wang, EB [1 ]
Shen, EH
Liu, ZR
Hu, CW
Xing, Y
Lin, YH
Jia, HQ
机构：
[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China
[2] Acad Sinica, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 10期
关键词：
ferric molybdenum phosphate; tunnel structure; synthesis; structural characterization;
D O I：
10.1016/S1387-7003(98)00101-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new ferric molybdenum phosphate containing a tunnel structure and crystallographically different clusters has been hydrothermally synthesized and structurally characterized by single crystal X-ray diffraction. A probe reaction of the oxidation of acetaldehyde with H2O2 using the tide compound as catalyst was carried out in a liquid-solid system, showing that the title compound had high catalytic activity in the reaction. (C) 1998 Elsevier Science S.A. All rights reserved.
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页码：382 / 385
页数：4
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