Recyclable Cu@C3N4-Catalyzed Hydroxylation of Aryl Boronic Acids in Water under Visible Light: Synthesis of Phenols under Ambient Conditions and Room Temperature

被引：68

作者：

Muhammad, Mehwish Hussain ^{[1
]}

Chen, Xiao-Lan ^{[1
]}

Liu, Yan ^{[1
,2
]}

Shi, Tao ^{[1
]}

Peng, Yuyu ^{[3
]}

Qu, Lingbo ^{[1
]}

Yu, Bing ^{[1
]}

机构：

[1] Zhengzhou Univ, Sch Chem Engn & Energy, Coll Chem, Zhengzhou 450001, Peoples R China

[2] Xinyang Agr & Forestry Univ, Coll Biol & Pharmaceut Engn, Xinyang 464000, Peoples R China

[3] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Changsha 410114, Peoples R China

来源：

ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2020年 / 8卷 / 07期

基金：

中国国家自然科学基金; 中国博士后科学基金;

关键词：

photocatalysis; hydroxylation; aqueous reaction; green oxidant; boronic acid; AEROBIC OXIDATIVE HYDROXYLATION; HIGHLY EFFICIENT CONVERSION; ARYLBORONIC ACIDS; IPSO-HYDROXYLATION; CATALYZED HYDROXYLATION; HETEROGENEOUS CATALYST; PHOTOREDOX CATALYSIS; ORGANIC FRAMEWORKS; HYDROGEN-PEROXIDE; IONIC LIQUID;

D O I：

10.1021/acssuschemeng.9b06010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A heterogeneous photocatalyst based on copper-doped g-C3N4 was developed for the oxidative hydroxylation of aryl boronic acids into phenols at room temperature under the irradiation of blue light (460 nm). The reaction proceeded efficiently in water as a green solvent and air as a green oxidant, giving various phenols as products with high yields in a short reaction time. Importantly, this heterogeneous catalyst can be used at least 5 times with the reactivities maintained.

引用

页码：2682 / 2687

页数：11

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