Red, Green, and Blue Luminescence by Carbon Dots: Full-Color Emission Tuning and Multicolor Cellular Imaging

被引:1768
作者
Jiang, Kai [1 ,2 ]
Sun, Shan [2 ]
Zhang, Ling [2 ]
Lu, Yue [2 ]
Wu, Aiguo [2 ]
Cai, Congzhong [1 ]
Lin, Hengwei [2 ]
机构
[1] Chongqing Univ, Dept Appl Phys, Chongqing 401331, Peoples R China
[2] Chinese Acad Sci, NIMTE, Div Funct Mat & Nanodevices, Ningbo 315201, Zhejiang, Peoples R China
关键词
bioimaging; carbon dots; full-color emission; luminescence; materials science; FLUORESCENCE QUANTUM YIELD; PHOTOLUMINESCENCE PROPERTIES; O-PHENYLENEDIAMINE; POLYMER DOTS; GRAPHENE; NANOPARTICLES; NITROGEN; NANOCRYSTALS; COMPLEXES; OXIDATION;
D O I
10.1002/anie.201501193
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A facile approach for preparation of photoluminescent (PL) carbon dots (CDs) is reported. The three resulting CDs emit bright and stable red, green and blue (RGB) colors of luminescence, under a single ultraviolet-light excitation. Alterations of PL emission of these CDs are tentatively proposed to result from the difference in their particle size and nitrogen content. Interestingly, up-conversion (UC) PL of these CDs is also observed. Moreover, flexible full-color emissive PVA films can be achieved through mixing two or three CDs in the appropriate ratios. These CDs also show low cytotoxicity and excellent cellular imaging capability. The facile preparation and unique optical features make these CDs potentially useful in numerous applications such as lightemitting diodes, full-color displays, and multiplexed (UC) PL bioimaging.
引用
收藏
页码:5360 / 5363
页数:4
相关论文
共 49 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]  
[Anonymous], 2010, Angewandte Chemie, DOI [10.1002/ange.200906623, DOI 10.1002/ANGE.200906623]
[3]  
[Anonymous], 2013, Angew, Chemie., DOI [DOI 10.1002/ANGE.201303927, 10.1002/ange.201303927]
[4]   Luminescent Carbon Nanodots: Emergent Nanolights [J].
Baker, Sheila N. ;
Baker, Gary A. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (38) :6726-6744
[5]   Carbon Nanoparticle-based Fluorescent Bioimaging Probes [J].
Bhunia, Susanta Kumar ;
Saha, Arindam ;
Maity, Amit Ranjan ;
Ray, Sekhar C. ;
Jana, Nikhil R. .
SCIENTIFIC REPORTS, 2013, 3
[6]   Taking advantage of luminescent lanthanide ions [J].
Bünzli, JCG ;
Piguet, C .
CHEMICAL SOCIETY REVIEWS, 2005, 34 (12) :1048-1077
[7]   Photoluminescence Properties of Graphene versus Other Carbon Nanomaterials [J].
Cao, Li ;
Meziani, Mohammed J. ;
Sahu, Sushant ;
Sun, Ya-Ping .
ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (01) :171-180
[8]   Carbon-Based Dots Co-doped with Nitrogen and Sulfur for High Quantum Yield and Excitation-Independent Emission [J].
Dong, Yongqiang ;
Pang, Hongchang ;
Yang, Hong Bin ;
Guo, Chunxian ;
Shao, Jingwei ;
Chi, Yuwu ;
Li, Chang Ming ;
Yu, Ting .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 52 (30) :7800-7804
[9]   Sandwich-structured upconversion nanoparticles with tunable color for multiplexed cell labeling [J].
Dou, Qingqing ;
Idris, Niagara Muhammad ;
Zhang, Yong .
BIOMATERIALS, 2013, 34 (06) :1722-1731
[10]   REFERENCE MATERIALS FOR FLUORESCENCE MEASUREMENT [J].
EATON, DF .
PURE AND APPLIED CHEMISTRY, 1988, 60 (07) :1107-1114