Preparation and Properties of Poly(ethylene terephthalate)/Inorganic Whiskers Composites

被引：11

作者：

Li, Nan ^{[1
]}

Luo, Ping ^{[1
]}

Liu, Kai ^{[1
]}

Chen, Li ^{[1
]}

Wang, Ke ^{[1
]}

Chen, Feng ^{[1
]}

Fu, Qiang ^{[1
]}

机构：

[1] Sichuan Univ, Dept Polymer Sci & Mat, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2011年 / 121卷 / 01期

基金：

中国国家自然科学基金;

关键词：

polymer-matrix composites (PMCs); mechanical properties; electron microscopy; thermal analysis; POTASSIUM TITANATE WHISKER; NANOCOMPOSITES; POLY(ETHYLENE-TEREPHTHALATE); CRYSTALLIZATION; POLYETHYLENE;

D O I：

10.1002/app.33729

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

To improve the crystallization and mechanical properties of poly(ethylene terephthalate) (PET), in this work, PET/ SiO2-MgO-CaO whiskers composites were prepared via in situ polymerization. The morphology, crystallization, and mechanical properties of the prepared composites were investigated. It was found that inorganic whiskers could be easily dispersed in PET matrix, as demonstrated by SEM and PLM. DSC and PLM observation indicated a strong nucleation capability of inorganic whiskers for PET. Mechanical analysis results showed that the glass transition temperature, tensile strength, and modulus of the composites were greatly improved. A possible chemical bonding between PET chains and the surface of whiskers was observed by FTIR, TGA, and sedimentation experiment. It could be the main reason for the good dispersion and improved properties of the prepared composites. This work is important for the application of PET due to the low cost but high reinforcing efficiency of this inorganic whisker. (c) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 121: 604-611, 2011

引用

页码：604 / 611

页数：8

共 30 条

[1] Poly(ethylene terephthalate) clay nanocomposites: Improved dispersion based on an aqueous ionomer [J].

Ammala, Anne ;

Bell, Carmen ;

Dean, Katherine .

COMPOSITES SCIENCE AND TECHNOLOGY, 2008, 68 (06) :1328-1337

[2] A new approach to prepare poly(ethylene terephthalate)/silica nanocomposites with increased molecular weight and fully adjustable branching or crosslinking by SSP [J].

Bikiaris, Dimitris ;

Karavelidis, Vassilis ;

Karayannidis, George .

MACROMOLECULAR RAPID COMMUNICATIONS, 2006, 27 (15) :1199-1205

[3] Clay functionalization and organization for delamination of the silicate tactoids in poly(L-lactide) matrix [J].

Chen, GX ;

Yoon, JS .

MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (11) :899-904

[4] The role of functional group on the exfoliation of clay in poly(L-lactide) [J].

Chen, GX ;

Choi, JB ;

Yoon, JS .

MACROMOLECULAR RAPID COMMUNICATIONS, 2005, 26 (03) :183-187

[5] Preparation and properties of organo-modifier free PET/MMT nanocomposites via monomer intercalation and in situ polymerization [J].

Chen, Zhaojun ;

Luo, Ping ;

Fu, Qiang .

POLYMERS FOR ADVANCED TECHNOLOGIES, 2009, 20 (12) :916-925

[6] Molecular level stabilization of poly(ethylene terephthalate) with nanostructured open cage trisilanolisobutyl-POSS [J].

Ciolacu, Flaviu Calin Ladasiu ;

Choudhury, Namita Roy ;

Dutta, Naba ;

Kosior, Edward .

MACROMOLECULES, 2007, 40 (02) :265-272

[7]

CUI P, 2008, J APP POLYM SCI, V110, P140

[8]

Fischer HR, 1999, ACTA POLYM, V50, P122, DOI 10.1002/(SICI)1521-4044(19990401)50:4<122::AID-APOL122>3.0.CO

[9]

2-X

[10] Functionalized multi-walled carbon nanotubes improve nonisothermal crystallization of poly(ethylene terephthalate) [J].

Gao, Yao ;

Wang, Yong ;

Shi, Jing ;

Bai, Hongwei ;

Song, Bo .

POLYMER TESTING, 2008, 27 (02) :179-188

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