Temperature gating of the ring-opening process in diarylethene molecular switches

被引：97
作者：
Dulic, Diana
Kudernac, Tibor
Puzys, Audrius
Feringa, Ben L.
van Wees, Bart J.
机构：
[1] Vienna Univ Technol, Photon Inst, A-1040 Vienna, Austria
[2] Univ Groningen, Mat Sci Ctr, Dept Appl Phys, NL-9747 AG Groningen, Netherlands
[3] Univ Groningen, Mol Inorgan Chem Stratingh Inst, Dept Organ, NL-9747 AG Groningen, Netherlands
[4] Mat Sci Ctr, NL-9747 AG Groningen, Netherlands
来源：
ADVANCED MATERIALS | 2007年 / 19卷 / 19期
关键词：
D O I：
10.1002/adma.200700161
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The ring-opening process in diarylethene molecular switches is suppressed with decreasing temperature, leading to the complete absence of the photoreaction below a cutoff temperature. By contrast, the reverse ring-closure process shows no significant temperature dependence above 115 K. Reversibility of the photoprocesses can be thus controlled by temperature (see figure).
引用
收藏
页码：2898 / +
页数：6
相关论文
共 56 条
[1]  
[Anonymous], 2001, MOL SWICHES
[2]   Three-state photochromic switching in a silyl bridged diarylethene dimer [J].
Areephong, Jetsuda ;
Browne, Wesley R. ;
Feringa, Ben L. .
ORGANIC & BIOMOLECULAR CHEMISTRY, 2007, 5 (08) :1170-1174
[3]   Photo- and electro-chromism of diarylethene modified ITO electrodes - towards molecular based read-write-erase information storage [J].
Areephong, Jetsuda ;
Browne, Wesley R. ;
Katsonis, Nathalie ;
Feringa, Ben L. .
CHEMICAL COMMUNICATIONS, 2006, (37) :3930-3932
[4]   Oxidative electrochemical switching in dithienylcyclopentenes, part 2: Effect of substitution and asymmetry on the efficiency and direction of molecular switching and redox stability [J].
Browne, WR ;
de Jong, JJD ;
Kudernac, T ;
Walko, M ;
Lucas, LN ;
Uchida, K ;
van Esch, JH ;
Feringa, BL .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (21) :6430-6441
[5]   Oxidative electrochemical switching in dithienylcyclopentenes, part 1: Effect of electronic perturbation on the efficiency and direction of molecular switching [J].
Browne, WR ;
de Jong, JJD ;
Kudernac, T ;
Walko, M ;
Lucas, LN ;
Uchida, K ;
van Esch, JH ;
Feringa, BL .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (21) :6414-6429
[6]   Highly fluorescent and photochromic diarylethene oligomer bridged by p-phenylenevinylene [J].
Cho, H ;
Kim, E .
MACROMOLECULES, 2002, 35 (23) :8684-8687
[7]  
CRANO JC, 1999, ORGANIC PHOTCHROMIC
[8]   Reversible optical transcription of supramolecular chirality into molecular chirality [J].
de Jong, JJD ;
Lucas, LN ;
Kellogg, RM ;
van Esch, JH ;
Feringa, BL .
SCIENCE, 2004, 304 (5668) :278-281
[9]  
Denekamp C, 1998, ADV MATER, V10, P1080, DOI 10.1002/(SICI)1521-4095(199810)10:14<1080::AID-ADMA1080>3.0.CO
[10]  
2-T
123456