Hollow Ferrocenyl Coordination Polymer Microspheres with Micropores in Shells Prepared by Ostwald Ripening

被引：152

作者：

Huo, Jia ^{[1
]}

Wang, Li ^{[1
]}

Irran, Elisabeth ^{[2
]}

Yu, Haojie ^{[1
]}

Gao, Jingming ^{[1
]}

Fan, Dengsen ^{[1
]}

Li, Bao ^{[1
]}

Wang, Jianjun ^{[1
]}

Ding, Wenbing ^{[1
]}

Amin, Abid Muhammad ^{[1
]}

Li, Chao ^{[1
]}

Ma, Liang ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem & Biol Engn, State Key Lab Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China

[2] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 48期

基金：

美国国家科学基金会;

关键词：

coordination polymers; metallocenes; hierarchical structures; hollow microspheres; microporous materials; METAL-ORGANIC FRAMEWORKS; TIO2; NANOSPHERES; STORAGE; PARTICLES; MICROPARTICLES; COPOLYMER; TOPOLOGY; INTERIOR; BEHAVIOR; SPHERES;

D O I：

10.1002/anie.201004745

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

From the inside out: Hollow ferrocenyl coordination polymer microspheres with microporous shells were prepared by a convenient and template-free approach. An Ostwald ripening mechanism is responsible for the formation of hollow cavities. The hierarchically hollow coordination polymer microspheres have potential applications in catalysis, drug delivery, and hydrogen storage. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9237 / 9241

页数：5

共 45 条

[1] Synthesis of ordered, uniform, macroporous carbons with mesoporous walls templated by aggregates of polystyrene spheres and silica particles for use as catalyst supports in direct methanol fuel cells [J].

Chai, GS ;

Shin, IS ;

Yu, JS .

ADVANCED MATERIALS, 2004, 16 (22) :2057-+

[2] Growth-Controlled Formation of Porous Coordination Polymer Particles [J].

Cho, Won ;

Lee, Hee Jung ;

Oh, Moonhyun .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (50) :16943-16946

[3] Fabrication of Microbeads with a Controllable Hollow Interior and Porous Wall Using a Capillary Fluidic Device [J].

Choi, Sung-Wook ;

Zhang, Yu ;

Xia, Younan .

ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (18) :2943-2949

[4] Systematic design of pore size and functionality in isoreticular MOFs and their application in methane storage [J].

Eddaoudi, M ;

Kim, J ;

Rosi, N ;

Vodak, D ;

Wachter, J ;

O'Keeffe, M ;

Yaghi, OM .

SCIENCE, 2002, 295 (5554) :469-472

[5] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[6] Gas-Sorption Properties of Cobalt(II)-Carborane-Based Coordination Polymers as a Function of Morphology [J].

Farha, Omar K. ;

Spokoyny, Alexander M. ;

Mulfort, Karen L. ;

Galli, Simona ;

Hupp, Joseph T. ;

Mirkin, Chad A. .

SMALL, 2009, 5 (15) :1727-1731

[7]

Ferey G., 2007, Angew. Chem, V119, P3323, DOI DOI 10.1016/j.jssc.2013.11.014

[8] Mixed-valence Li/Fe-based metal-organic frameworks with both reversible redox and sorption properties [J].

Ferey, Gerard ;

Millange, Franck ;

Morcrette, Mathieu ;

Serre, Christian ;

Doublet, Marie-Liesse ;

Greneche, Jean-Marc ;

Tarascon, Jean-Marie .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (18) :3259-3263

[9]

GUO D, 2002, J CHEM SOC DA

[10]

Huo J, 2008, J PHYS CHEM B, V112, P11490, DOI [10.1021/jp7121888, 10.1021/JP7121888]

← 1 2 3 4 5 →