Hollow Ferrocenyl Coordination Polymer Microspheres with Micropores in Shells Prepared by Ostwald Ripening

被引:150
作者
Huo, Jia [1 ]
Wang, Li [1 ]
Irran, Elisabeth [2 ]
Yu, Haojie [1 ]
Gao, Jingming [1 ]
Fan, Dengsen [1 ]
Li, Bao [1 ]
Wang, Jianjun [1 ]
Ding, Wenbing [1 ]
Amin, Abid Muhammad [1 ]
Li, Chao [1 ]
Ma, Liang [1 ]
机构
[1] Zhejiang Univ, Dept Chem & Biol Engn, State Key Lab Chem Engn, Hangzhou 310027, Zhejiang, Peoples R China
[2] Tech Univ Berlin, Inst Chem, D-10623 Berlin, Germany
基金
美国国家科学基金会;
关键词
coordination polymers; metallocenes; hierarchical structures; hollow microspheres; microporous materials; METAL-ORGANIC FRAMEWORKS; TIO2; NANOSPHERES; STORAGE; PARTICLES; MICROPARTICLES; COPOLYMER; TOPOLOGY; INTERIOR; BEHAVIOR; SPHERES;
D O I
10.1002/anie.201004745
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
From the inside out: Hollow ferrocenyl coordination polymer microspheres with microporous shells were prepared by a convenient and template-free approach. An Ostwald ripening mechanism is responsible for the formation of hollow cavities. The hierarchically hollow coordination polymer microspheres have potential applications in catalysis, drug delivery, and hydrogen storage. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:9237 / 9241
页数:5
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