Pulsed Electrodeposition and Properties of Nickel-Based Composite Coatings Modified with Graphene Oxide

被引:11
作者
Tseluikin, Vitaly [1 ]
Dzhumieva, Asel [1 ]
Tikhonov, Denis [1 ]
Yakovlev, Andrey [1 ]
Strilets, Anastasia [1 ]
Tribis, Alena [1 ]
Lopukhova, Marina [1 ]
机构
[1] Yuri Gagarin State Tech Univ Saratov, Engels Technol Inst, Saratov 410054, Russia
关键词
pulsed electrolysis mode; nickel; graphene oxide; structure; microhardness; corrosion properties; WEAR BEHAVIOR; NI; PARTICLES; CORROSION; CODEPOSITION; DEPOSITION; RESISTANCE; REVERSE;
D O I
10.3390/coatings12050656
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Composite electrochemical coatings (CECs) on the basis of nickel modified with multilayer graphene oxide (GO) were deposited from a sulfate-chloride electrolyte in pulsed electrolysis mode. The microstructure of these CECs was studied by X-ray phase analysis and scanning electron microscopy. It was found that the microhardness of nickel-GO CECs increases by approximately 1.40 times compared to pure nickel. The corrosion-electrochemical behavior of nickel-GO composite coatings in 0.5 M H2SO4 was studied. Based on tests in 3.5% NaCl, it was found that the addition of graphene oxide particles into the matrix of nickel electrodeposits, increases their corrosion resistance by 1.40-1.50 times. This can be explained by the uniformity of the distribution of GO in the nickel matrix, which contributes to the reduction in grain size, as well as the impermeability and stability of graphene oxide.
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页数:8
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