Synthesis and structure of a molecular barium aminebis(phenolate) and its application as an initiator for ring-opening polymerization of cyclic esters

被引:55
作者
Davidson, Matthew G. [1 ]
O'Hara, Charles T.
Jones, Matthew D.
Keir, Callum G.
Mahon, Mary F.
Kociok-Kohn, Gabriele
机构
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
[2] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland
关键词
D O I
10.1021/ic700583e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and structural characterization of an unusual trinuclear barium aminebis(phenolate) complex are reported along with its application as an initiator for the ring-opening polymerization of epsilon-caprolactone and L-lactide.
引用
收藏
页码:7686 / 7688
页数:3
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