The interpretation of the parameters of the equation used for the extrapolation of apparent molar volumes of the non-electrolyte (solutes) to the infinite dilution

被引：17

作者：

Wawer, Jaroslaw ^{[1
]}

Krakowiak, Joanna ^{[1
]}

机构：

[1] Gdansk Univ Technol, Fac Chem, Dept Phys Chem, Narutowicza Str 11-12, PL-80233 Gdansk, Poland

来源：

JOURNAL OF MOLECULAR LIQUIDS | 2019年 / 296卷

关键词：

Volumetric studies; Density measurements; Apparent molar volume; Standard partial molar volume; AQUEOUS CITRIC-ACID; L-PHENYLALANINE; L-THREONINE; BEHAVIOR; GLYCINE; WATER; VISCOSITY; ALANINE; DRUG;

D O I：

10.1016/j.molliq.2019.111765

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The paper discusses how to interpret the parameters of the basic equation used for the extrapolation of the apparent molar volume of the solute to infinite dilution. The common misunderstandings and oversimplifications have been pointed out. We present the alternative ways of the data interpretation that can be used to eliminate these obvious but frequent mistakes. (C) 2019 Elsevier B.V. All rights reserved.

引用

页数：2

共 29 条

[21] EMPIRICAL CORRELATIONS OF PARTIAL MOLAR VOLUMES AT INFINITE DILUTION OF ORGANIC SOLUTES AND TRANSITION-STATES FOR SN2 HYDROLYSIS AND ETHANOLYSIS OF NORMAL-ALKYL BROMIDES
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JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1989, (06): : 563 - 571
[22] The development of a response surface model for the determination of infinite dilution partial molar volumes and excess volumes from dilute multi-component data alone. Implications for the characterization of non-isolatable solutes in complex homogeneous reactive systems
Tjahjono, M
Guo, LF
Garland, M
CHEMICAL ENGINEERING SCIENCE, 2005, 60 (12) : 3239 - 3249
[23] EMPIRICAL CORRELATIONS OF PARTIAL MOLAR VOLUMES AT INFINITE DILUTION OF ORGANIC SOLUTES AND TRANSITION-STATES FOR SN1 AND SN2 ETHANOLYSIS OF ALKYL-HALIDES
ITSUKI, H
YAMAMOTO, H
OKAZAKI, H
TERASAWA, S
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1990, (09): : 1545 - 1550
[24] Prediction of the infinite-dilution partial molar volumes of organic solutes in supercritical carbon dioxide using the Kirkwood-Buff fluctuation integral with the hard sphere expansion (HSE) theory
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Korean Journal of Chemical Engineering, 2005, 22 : 452 - 456
[25] Prediction of the infinite-dilution partial molar volumes of organic solutes in supercritical carbon dioxide using the Kirkwood-Buff fluctuation integral with the hard sphere expansion (HSE) theory
Kwon, YJ
Lee, WG
KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2005, 22 (03) : 452 - 456
[26] Correlation and prediction of infinite-dilution partial molar volumes of organic solutes in SC CO2 using the Peng-Robinson and PHCT equations of state and the LCVM EOS/G(E) model
Coutsikos, P
Magoulas, K
Tassios, D
Cortesi, A
Kikic, I
JOURNAL OF SUPERCRITICAL FLUIDS, 1997, 11 (1-2): : 21 - 35
[27] Comparison of the Pitzer and Huckel Equation Frameworks for Activity Coefficients, Osmotic Coefficients, and Apparent Molar Relative Enthalpies, Heat Capacities, and Volumes of Binary Aqueous Strong Electrolyte Solutions at 25 °C
Rowland, Darren
May, Peter M.
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2015, 60 (07): : 2090 - 2097
[28] VOLUMETRIC PROPERTIES OF AQUEOUS 1-1-ELECTROLYTES NEAR AND ABOVE THE CRITICAL-TEMPERATURE OF WATER .3. EXPERIMENTAL DENSITIES AND APPARENT MOLAR VOLUMES OF CSBR(AQ) TO THE TEMPERATURE 725.5-K AND THE PRESSURE 38.0 MPA, COMPARISON WITH OTHER 1-1-ELECTROLYTES, AND EXTRAPOLATIONS TO INFINITE DILUTION FOR NACL(AQ)
MAJER, V
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JOURNAL OF CHEMICAL THERMODYNAMICS, 1994, 26 (11): : 1143 - 1166
[29] Densities and Apparent Molar Volumes of Atmospherically Important Electrolyte Solutions. 1. The Solutes H2SO4, HNO3, HCl, Na2SO4, NaNO3, NaCl, (NH4)2SO4, NH4NO3, and NH4Cl from 0 to 50 °C, Including Extrapolations to Very Low Temperature and to the Pure Liquid State, and NaHSO4, NaOH, and NH3 at 25 °C
Clegg, S. L.
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JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (15): : 3393 - 3460

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