The interpretation of the parameters of the equation used for the extrapolation of apparent molar volumes of the non-electrolyte (solutes) to the infinite dilution

被引：17
|
作者：
Wawer, Jaroslaw [1 ]
Krakowiak, Joanna [1 ]
机构：
[1] Gdansk Univ Technol, Fac Chem, Dept Phys Chem, Narutowicza Str 11-12, PL-80233 Gdansk, Poland
来源：
JOURNAL OF MOLECULAR LIQUIDS | 2019年 / 296卷
关键词：
Volumetric studies; Density measurements; Apparent molar volume; Standard partial molar volume; AQUEOUS CITRIC-ACID; L-PHENYLALANINE; L-THREONINE; BEHAVIOR; GLYCINE; WATER; VISCOSITY; ALANINE; DRUG;
D O I：
10.1016/j.molliq.2019.111765
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The paper discusses how to interpret the parameters of the basic equation used for the extrapolation of the apparent molar volume of the solute to infinite dilution. The common misunderstandings and oversimplifications have been pointed out. We present the alternative ways of the data interpretation that can be used to eliminate these obvious but frequent mistakes. (C) 2019 Elsevier B.V. All rights reserved.
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