Complexes of the [K(18-Crown-6)]+ Fragment with Bis(tetrazolyl)borate Ligands: Unexpected Boron-Nitrogen Bond Isomerism and Associated Enforcement of κ3-N,N′,H-Ligand Chelation

被引：19

作者：

Lu, Dongmei ^{[1
]}

Winter, Charles H. ^{[1
]}

机构：

[1] Wayne State Univ, Dept Chem, Detroit, MI 48202 USA

来源：

INORGANIC CHEMISTRY | 2010年 / 49卷 / 13期

关键词：

RAY CRYSTAL-STRUCTURE; METAL-COMPLEXES; DIHYDRIDOBIS(3-NITRO-1,2,4-TRIAZOLYL)BORATE LIGAND; TRIS(PYRAZOLYL)BORATE LIGANDS; STRUCTURAL-CHARACTERIZATION; COORDINATION POLYMERS; POTASSIUM COMPLEXES; SALTS; ANION; ETA(2)-PYRAZOLATO;

D O I：

10.1021/ic100959j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses and solid-state structures of K(BH2(RCN4)(2))-(18-crown-6) (R = H, Me, NMe2, and NiPr2) are described. Complexes where R = H and Me have B-N bonds to N-1 of the tetrazolyl groups and form one-dimensional polymers, whereas those with R = NMe2 and NiPr2 possess isomeric B-N bonds to N-2 of the tetrazolyl moieties and adopt chelating kappa(3)-N,N',H-coordination modes to the potassium ion.

引用

页码：5795 / 5797

页数：3