Speciation of 129I and 127I in seawater and implications for sources and transport pathways in the North Sea

Surface seawater samples collected from the North Sea and English Channel were analyzed for total I-129 and I-127, as well as for iodide and iodate. Relatively high I-129 concentrations (2-3 x 10(11) atoms/L) were observed in the northern part of the English Channel and in the southeastern North Sea. The atomic ratio of I-129/I-121 decreases from the eastern (1.0-1.9 x 10(-6)) to the western (4-6 x 10(-8)) parts of the North Sea and from the northeastern 0.5 x 10(-6)) to southwestern (1-5 x 10(-8)) parts of the English Channel. The ratios of iodide to iodate are 0.1-0.5 and 0.5-1.6 for I-127 and I-129, respectively, in open seawaters, whereas these ratios range from 0.6 to 1.3 and 0.8 to 2.2, respectively, in coastal waters. The results suggest that (1) imprints of the La Hague facility dominates the 129 1 distribution in the surface water of the North Sea, (2) reduction of iodate to iodide is relatively fast during the transport to the European continental coast, (3) oxidation of newly produced 129I(-) to (IO3-)-I-129 is insignificant during water exchange between the coastal area and open sea, (4) reduction of iodate and oxidation of iodide in the open sea seems to be a slow process.