The synthesis and photoluminescence of three porous metal-organic frameworks

被引：1
|
作者：
Wang, Yu [1 ]
Zeng, Hui-Ming [1 ]
Mao, Wei-Tao [1 ]
Wang, Xiao-Juan [1 ]
Jiang, Zhan-Guo [1 ]
Zhan, Cai-Hong [1 ]
Feng, Yun-Long [1 ]
机构：
[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Inst Phys Chem, Key Lab,Minist Educ Adv Catalysis Mat, Jinhua 321004, Zhejiang, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2021年 / 129卷
基金：
中国国家自然科学基金;
关键词：
Metal-organic framework; 3,5-bis(3,5-dicarboxylphenxoy)benoic acid; Crystal structure; Luminescence;
D O I：
10.1016/j.inoche.2021.108613
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three new metal-organic frameworks (MOFs) based on a new organic ligand, 3,5-bis(3,5-dicarboxylphenxoy) benoic acid (H5L), {[Cd5L2(H2O)(6)]center dot 4H(2)O center dot 6DMF}(n) (1), {[Zn5L2(H2O)(5)]center dot 11H(2)O center dot 8DMA}(n) (2) and {[Zn3L(H2O)3(OH)]center dot 12H(2)O center dot 8DMF}(n) (3), have been synthesized and characterized by single-crystal X-ray diffraction, TGA and FTIR. 1 exhibits a (4,8)-connected 3D networks with Schlafli symbol of (4(10).6(16). 8(3))(4(5).6)(2). 2 shows a 3D networks with a type of tetragonal prism cage (9.5 x 9.5 x 14.6 angstrom). 3 exhibits a (4,4)-connected 3D networks with Schlafli symbol of (6(6)). The fluorescence properties of 1-3 are discussed.
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页数：7
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