The synthesis and photoluminescence of three porous metal-organic frameworks

被引：1

作者：

Wang, Yu ^{[1
]}

Zeng, Hui-Ming ^{[1
]}

Mao, Wei-Tao ^{[1
]}

Wang, Xiao-Juan ^{[1
]}

Jiang, Zhan-Guo ^{[1
]}

Zhan, Cai-Hong ^{[1
]}

Feng, Yun-Long ^{[1
]}

机构：

[1] Zhejiang Normal Univ, Coll Chem & Life Sci, Inst Phys Chem, Key Lab,Minist Educ Adv Catalysis Mat, Jinhua 321004, Zhejiang, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2021年 / 129卷

基金：

中国国家自然科学基金;

关键词：

Metal-organic framework; 3,5-bis(3,5-dicarboxylphenxoy)benoic acid; Crystal structure; Luminescence;

D O I：

10.1016/j.inoche.2021.108613

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three new metal-organic frameworks (MOFs) based on a new organic ligand, 3,5-bis(3,5-dicarboxylphenxoy) benoic acid (H5L), {[Cd5L2(H2O)(6)]center dot 4H(2)O center dot 6DMF}(n) (1), {[Zn5L2(H2O)(5)]center dot 11H(2)O center dot 8DMA}(n) (2) and {[Zn3L(H2O)3(OH)]center dot 12H(2)O center dot 8DMF}(n) (3), have been synthesized and characterized by single-crystal X-ray diffraction, TGA and FTIR. 1 exhibits a (4,8)-connected 3D networks with Schlafli symbol of (4(10).6(16). 8(3))(4(5).6)(2). 2 shows a 3D networks with a type of tetragonal prism cage (9.5 x 9.5 x 14.6 angstrom). 3 exhibits a (4,4)-connected 3D networks with Schlafli symbol of (6(6)). The fluorescence properties of 1-3 are discussed.

引用

页数：7

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